首页|TiO2/AC光催化降解PTA精制废水的实验研究

TiO2/AC光催化降解PTA精制废水的实验研究

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针对精对苯二甲酸(PTA)精制废水净化处理难问题,提出一种新型光催化降解处理方法.采用两步法制备TiO2/活性炭(AC)复合催化剂,并利用X-射线衍射光谱(XRD)、N2吸附脱附和扫描电镜(SEM)对制备的复合催化剂进行表征.在光反应装置中进行光催化降解实验,考察TiO2/AC的光催化性能.结果表明:锐钛矿晶型的TiO2分散于AC丰富的微孔和中孔中;最佳光催化反应条件为焙烧温度为500 ℃,AC粒径为(0.2,0.3]mm,紫外灯功率为40 W,TiO2负载量为11%,催化剂质量浓度为7 g/L,光照时间7 h,此时PTA精制废水的化学需氧量(COD)去除率达64.24%;同时,TiO2/AC复合催化剂展现出良好的重复使用性能,证明了 TiO2/AC光催化处理方法的可行性和高效性.
Photocatalytic Degradation of PT A Refined Waste water by TiO2/AC
A new photocatalytic treatment is proposed to deal with purified terephthalic acid(PTA)refined wastewater.The two-step method is used to prepare TiO2/activated carbon(AC)composite catalyst,then TiO2/AC are examined by X-ray diffraction(XRD),N2 adsorption desorption,and scanning electron microscopy(SEM).Under UV light,the photocatalytic performance of TiO2/AC is examined through the degradation of PTA refined wastewater.The experimental results show that the rutile crystalline TiO2 is distributed in the numerous micropores and mesopores of AC.The optimal photocatalytic reaction conditions are as follows:The COD removal rate of PTA refined wastewater is 64.24%at a calcination temperature of 500 ℃,with AC particle size of 0.2~0.3 mm,UV light power of 40 W,TiO2 loading of 11%,catalyst concentration of 7 g/L,and light duration of 7 hours.Additionally,TiO2/AC composite catalysts display remarkable reusability,and such treatment proves to be feasible and effective.

TiO2activated carbonphotocatalysisPTArefined wastewaterdegradation treatment

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江苏科本药业有限公司 总经理办公室,江苏 南通 226221

TiO2 活性炭 光催化 PTA 精制废水 降解处理

2024

南通职业大学学报
南通职业大学

南通职业大学学报

影响因子:0.366
ISSN:1008-5327
年,卷(期):2024.38(2)
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