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设施土壤磷素固持材料的选择与应用研究进展

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我国设施土壤磷素高量积累继而流失是造成相邻水体富营养化的一个重要原因。施用磷素固持材料是有效减少土壤磷流失的措施之一,本文对比分析了室内条件下几类磷素固持材料(黏土矿物类、铁铝类、钙镁类和其他类)对磷酸盐的吸附量和吸附机制,总结了设施土壤中添加磷素固持材料对土壤有效磷含量、磷形态和磷素淋洗量的影响。基于材料的易获取性、安全性、价格以及被固持磷素的再利用性,提出了不同土壤中适宜施用的磷素固持材料。结果表明,添加磷素固持材料能通过物理、化学等作用吸附土壤磷,降低磷移动性。一般而言,铁铝类、钙镁类材料的磷素吸附量和吸附键能高于黏土矿物类,而改性生物炭材料的磷吸附量和强度常取决于改性物质。施入土壤后,铁铝类、钙镁类材料能快速降低土壤磷活性,进而减少磷的移动和流失,然而过量施用铁铝类材料可能影响作物正常生长及其对磷的吸收,适宜钙镁比的材料不仅能固持土壤磷,而且不影响作物对磷素的吸收利用。因此,在磷含量极高的设施石灰性土壤上,推荐适量施用铁铝类材料;在酸性土壤上,建议施用适宜钙镁比的材料,固持土壤磷并保持磷的有效性;黏土类材料则在磷含量适中的土壤上较为适用。此外,利用废弃物作为磷素固持材料,可在减少土壤磷流失的同时实现废弃物资源化利用,具有较好的应用前景。
Selection and application of phosphorus retention materials in protected vegetable field soils
Soil phosphorus(P)loss from protected vegetable fields(PVFs)can lead to the eutrophication of connected water bodies in China.This study focuses on effectively reducing phosphorus loss in the facility soil and improving phosphorus retention capacity.The sorption capacities and mechanism of P sorbed by different phosphorus retention materials(PRMs)(clay minerals,Fe/Al oxides,Ca/Mg oxides,and other materials)were compared.Moreover,the variation of soil P availability,P species,and P leaching loss by PRMs addition were also ascertained.Furthermore,the applicability of PRMs was evaluated by considering their accessibility,safety,price,and reusability.Studies have shown that the addition of PRMs can adsorb soil phosphorus through physical or chemical effects and reduce the mobility of phosphorus.Typically,the sorption bond energy of Fe/Al and Ca/Mg oxides is generally higher than that of clay minerals.The P sorbing capacities of pristine biochar are relatively low,while the P sorption capacity of modified biochar mainly depends on the modified material.After application to the soil,Ca/Mg oxides and Fe/Al oxides materials can rapidly reduce the activity of soil phosphorus.However,excessive application of Fe/Al oxide materials may affect the growth of crops.Adjusting the calcium and magnesium ratio of Ca/Mg oxide materials can not only hold the soil phosphorus but also not affect the absorption and utilization of crops.Therefore,appropriate Fe/Al oxide application can be recommended in P-enriched calcareous soil.In acidic soils,it is suggested to apply PRMs with suitable calcium and magnesium ratios to reduce the P losses but not affect the P availability.The clay materials can be used in soils with moderate P content.Besides,using waste as PRMs may reduce the loss of soil phosphorus and increase the resource utilization of waste,which has a great application prospect.

protected vegetable field soilsphosphorusphosphorus retention materialphosphorus sorbing capacityphosphorus species

尹贵明、樊秉乾、王洪媛、刘宏斌、武淑霞、陈清

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农田土壤污染防控与修复北京市重点实验室,中国农业大学资源与环境学院,北京 100193

中国农业科学院农业资源与农业区划研究所/农业农村部面源污染控制重点实验室,北京 100081

设施土壤 磷素固持材料 磷吸附量 磷形态

国家重点基础研究发展计划项目国家自然科学基金青年科学基金项目

2022YFD170070042207395

2024

农业资源与环境学报
农业部环境保护科研监测所,中国农业生态环境保护协会

农业资源与环境学报

CSTPCD北大核心
影响因子:1.059
ISSN:2095-6819
年,卷(期):2024.41(4)
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