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二甲醚水蒸气重整制氢试验

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将铜基催化剂CNZ-1和分子筛HZSM-5按一定比例,采用机械混合法制成二甲醚水蒸气重整催化剂,分别考察了水和二甲醚流量、反应温度、催化剂用量等对二甲醚水蒸气重整制氢的影响。结果表明:常压条件下,随着二甲醚流量增大,氢气的产量先变大再变小;在250~500℃的温度范围内,随着反应温度的升高,氢气的产率增大,二甲醚转化率最高可接近100%;CO体积分数随着反应温度的升高而减小;试验条件下,加大催化剂用量对氢气的产率影响不大,但可大幅度提高二甲醚的转化率。
Experiment on the Performance of Steam Reforming by Dimethyl-ether
The performance of stream reforming for rich hydrogen co-gas by dimethyl-ether (DME)was experimental studied. The multiunit catalyst which was formed with copper-based catalyst (named CNZ-1) and aluminium/zinc based molecular sieve (named HZSM-5) by means of mechanical mixing, was used. The parameters such as flow rate of reactants including water steam and DME, the reaction temperature as well as the catalyst amount influence on the reforming performance were investigated. Results show that under normal pressure, when DME flow rate increases, the yield of hydrogen increases at the beginning and then decreases. At the range from 250℃ to 500℃, the production rate of hydrogen increases with the increasing of temperature, and the maximum conversion rate of DME almost reaches 100%; the volume fraction of carbon monoxide decreases as the reaction temperature rises; although larger amount of catalyst has no influences on hydrogen production rate under the test conditions, it can improve effectively the conversion rate of DME.

DMESteam reformingHydrogen

张武高、陆伟东、闫应

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上海交通大学机械与动力工程学院,上海,200240

二甲醚 水蒸气重整 制氢

国家自然科学基金

50676056

2010

农业机械学报
中国农业机械学会 中国农业机械化科学研究院

农业机械学报

CSTPCDCSCD北大核心EI
影响因子:1.904
ISSN:1000-1298
年,卷(期):2010.41(2)
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