首页|紫外可见-光谱库在农药除草剂隐性成分排查中的应用

紫外可见-光谱库在农药除草剂隐性成分排查中的应用

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通过高效液相色谱法,建立了113种常规除草剂的标准紫外-可见光谱图库,检测除草剂中的隐性成分。以乙腈磷酸水为流动相的梯度洗脱对除草剂隐性成分进行定性分析。通过光谱库对2个农药除草剂进行了隐性成分鉴定,检出了敌稗、噁唑酰草胺和2甲4氯3种隐性成分。此方法能够快速准确的查出除草剂中添加的隐性成分,特征性和专属性很强,能够克服保留时间定性时容易造成假阳性的结果;该方法操作简单、检测效率高、时间短和成本低,适合于农药分析人员。
Application of UV-visible Spectral Library in Identifying Hidden Ingredients in Herbicides
This study outlines the development of a standard UV-visible spectral library comprising 113 conventional herbicides aimed at identifying hidden ingredients in herbicides.Employing a mobile phase of acetonitrile and water with ortho-phosphoric acid,qualitative analysis of herbicide hidden ingredients was performed by gradient elution.Hidden ingredients were identified on two pesticide herbicides using the spectral library,revealing 3 hidden ingredients:propanil,metamifop and methylchloro phenoxyacetic acid.This method enables quick and accurate detection of hidden ingredients added in herbicides,providing strong characteristic and specificity and overcoming false positive results inherent in retention time-based qualitative analysis.The simplicity of operation,high detection efficiency,short analysis time,and cost-effectiveness render this method suitable for pesticide analysts.

high-performance liquid chromatographyultraviolet-visible spectrum librarypesticidehidden ingredients

陈颖、陈一萍、刘小锋、廖丽萍、傅洪涛

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湖南化工研究院有限公司 国家农药创制工程技术研究中心,湖南 长沙 410014

湖南化肥农药质量监督检验授权站,湖南 长沙 410014

高效液相色谱仪 紫外-可见光谱库 农药 隐性成分

2024

农药科学与管理
农业部农药检定所

农药科学与管理

CSTPCD
影响因子:0.511
ISSN:1002-5480
年,卷(期):2024.45(4)
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