首页|Bi2O3/CaFe2O4 Z型异质结材料光催化降解氧氟沙星

Bi2O3/CaFe2O4 Z型异质结材料光催化降解氧氟沙星

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利用溶剂热法合成了Z型异质结Bi2O3/CaFe2O4 复合催化剂.采用多种表征手段对其晶体结构、形貌和性能进行了表征,并以氧氟沙星(OFX)为降解对象考察了 Bi2O3/CaFe2O4 复合催化剂的光催化活性.结果表明:Bi2O3 负载在 CaFe2O4 表面,构建了 Z型异质结构,这种结构能加速无效光生载流子的复合,促进有效光生载流子的分离,提升 Bi2O3/CaFe2O4 复合催化剂的可见光催化活性;Bi2O3/CaFe2O4 复合催化剂对 OFX的降解效果明显优于纯 Bi2O3 和 CaFe2O4.在 Bi2O3 负载量为 5%时,Bi2O3/CaFe2O4 对 OFX的降解效果最好,降解率可达 78.7%,经过 4 次循环,依然可达到 62.5%,说明其理化性能稳定,能够长期稳定循环使用.
BI2O3/CAFE2O4 Z-SCHEME HETEROJUNCTION MATERIAL FOR PHOTOCATALYTIC DEGRADATION OF OFLOXACIN
Z-type heterojunction Bi2O3/CaFe2O4 composite catalyst was synthesized through solvothermal method.This composite cata-lyst was extensively characterized by various methods,including structure,morphology and properties.The photocatalytic activity of Bi2O3/CaFe2O4 composite catalyst was tested with ofloxacin(OFX)as the degradation target.The results indicated that Bi2O3 is loaded on the surface of CaFe2O4 to form a Z-type heterojunction structure,which accelerates the recombination of ineffective photogenerated car-riers,promotes the separation of effective photogenerated carriers,and significantly enhances the visible light catalytic activity of the Bi2O3/CaFe2O4 composite catalyst.In comparison to pure Bi2O3 and CaFe2O4,Bi2O3/CaFe2O4 composite catalyst exhibited a better degradation effect on OFX.Notably,when the Bi2O3 load is 5%,Bi2O3/CaFe2O4 exhibited the best degradation effect on OFX,with a degradation rate of up to 18.7%.After four cycles,this rate still remained at 62.5%,indicating that its physical and chemical proper-ties are stable and can be used stably for a long time.

Bi2 O3CaFe2 O4photocatalysisofloxacin

叶红勇、杜佳、杨培渊、王明辉、左广玲

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南阳理工学院生物与化学工程学院 河南 南阳 473000

河南省工业微生物资源与发酵利用重点实验室 河南 南阳 473000

Ag3PO4 CaFe2O4 光催化 氧氟沙星

2024

南阳理工学院学报
南阳理工学院

南阳理工学院学报

CHSSCD
影响因子:0.178
ISSN:1674-5132
年,卷(期):2024.16(4)