首页|Growing Biomorphic Transition Metal Dichalcogenides and Their Alloys Toward High Permeable Membranes and Efficient Electrocatalysts Applications

Growing Biomorphic Transition Metal Dichalcogenides and Their Alloys Toward High Permeable Membranes and Efficient Electrocatalysts Applications

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3D architecratured transition metal dichalcogenides constructed by atomically thin layers are appealing building blocks in various applications,such as catalysts,energy storage,conversions,sensors,and so on.However,the direct growth of 3D transition metal dichalcogenides architectures with high crystal quality and well-controlled size/thickness remains a huge challenge.Herein,we report a facile,highly-repeatable,and versatile chemical vapor deposition strategy,for the mass production of high-quality 3D-architecratured transition metal dichalcogenides(e.g.,MoS2,WS2,and ReS2)and their alloys(e.g.,WxMo(1-x)S2 and RexMo(1-x)S2)nanosheets on naturally abundant and low-cost diatomite templates.Particularly,the purified transition metal dichalcogenides products exhibit unique and designable 3D biomorphic hierarchical microstructures,controllable layer thicknesses,tailorable chemical compositions,and good crystallinities.The weak interlayer interactions endow them with good dispersity in solutions to form stable additive-free inks for solution-processing-based applications,for example,high-permeable and high-stable separation membranes for water purification,and efficient electrocatalysts for hydrogen evolution reactions.This work paves ways for the low-cost,mass production of versatile transition metal dichalcogenides powder-like materials with designable structures and properties,toward energy/environmental-related applications and beyond.

biomorphicchemical vapor depositionhydrogen evolution reactionsseparation membranestransition metal dichalcogenides

Lijie Zhu、Yahuan Huan、Zhaoqian Zhang、Pengfei Yang、Jingyi Hu、Yuping Shi、Fangfang Cui、Yanfeng Zhang

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School of Materials Science and Engineering,Peking University,Beijing 100871,China

State Key Laboratory of Separation Membranes and Membrane Process,School of Materials Science and Engineering,Tiangong University,Tianjin 300387,China

国家自然科学基金国家自然科学基金国家自然科学基金国家自然科学基金国家重点研发计划北京市自然科学基金中国博士后科学基金

520210065192520151991344519913402018YFA070370021920212021M690195

2023

能源与环境材料(英文)

能源与环境材料(英文)

CSCD
ISSN:
年,卷(期):2023.6(3)
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