皮革与化工2024,Vol.41Issue(1) :9-14.

基于均匀设计的无铬复鞣工艺设计与优化

Design and Optimization of Leather Chrome-free Retanning Process Based on Uniform Design

孙辉永 林可心 温会涛 刘琳 吴渝玉 但卫华
皮革与化工2024,Vol.41Issue(1) :9-14.

基于均匀设计的无铬复鞣工艺设计与优化

Design and Optimization of Leather Chrome-free Retanning Process Based on Uniform Design

孙辉永 1林可心 1温会涛 1刘琳 1吴渝玉 1但卫华2
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作者信息

  • 1. 福建省皮革绿色设计与制造重点试验室,福建晋江 362271;中国轻工业制革绿色工程实验室,福建晋江 362271;兴业皮革科技股份有限公司国家企业技术中心,福建晋江 362261
  • 2. 兴业皮革科技股份有限公司国家企业技术中心,福建晋江 362261;四川大学制革清洁技术国家工程研究中心,四川成都 610065
  • 折叠

摘要

为提高皮革复鞣工艺的生态性能,以锆-铝-钛鞣白湿革为原料皮,以皮革的热收缩温度、撕裂强度、感官性能和复鞣排放废液中的COD含量作为评价指标,设计并优化基于改性戊二醛、锆铝钛配合鞣剂和阳离子油的无铬复鞣工艺.结果表明,当改性戊二醛鞣剂用量为 2%、锆-铝-钛配合鞣剂用量为2%、阳离子油用量为0.4%时,复鞣效果和生态性能好,复鞣后的坯革也具有较好的耐热性能、感官性能和物理性能.这为皮革的生态设计提供了一种新思路.

Abstract

To improve the ecological performance of leather retanning process,using zirconium-aluminum-titanium tanned wet-white as raw material,taking the obtained leather's thermal shrinkage temperature,tear strength,sensory performance and COD content in retanning effluent as evaluation indicators,a chrome-free retanning process based on modified glutaraldehyde,zirconium-aluminum-titanium complex tanning agent and cationic oil was designed and optimized.The results showed that when the amount of modified glutaraldehyde tanning agent was 2%,the amount of zirconium-aluminum-titanium complex tanning agent was 2%,and the amount of cationic oil was 0.4%,the retanning effect and ecological performance were good,and the retanned crust leather also had good heat resistance,sensory performance and physical properties.It provides a new method for the eco-design of ecological leather.

关键词

制革工程/无铬复鞣/均匀设计/生态皮革/生态设计

Key words

leather engineering/chrome-free retanning process/uniform design/ecological leather/eco-design

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基金项目

福建省科技计划项目(2022H4014)

福建省科技计划项目(2023L3053)

出版年

2024
皮革与化工
中国皮革协会 全国皮革化工材料研究开发中心

皮革与化工

CSTPCD
影响因子:0.396
ISSN:1674-0939
参考文献量11
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