首页|基于均匀设计的无铬复鞣工艺设计与优化

基于均匀设计的无铬复鞣工艺设计与优化

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为提高皮革复鞣工艺的生态性能,以锆-铝-钛鞣白湿革为原料皮,以皮革的热收缩温度、撕裂强度、感官性能和复鞣排放废液中的COD含量作为评价指标,设计并优化基于改性戊二醛、锆铝钛配合鞣剂和阳离子油的无铬复鞣工艺.结果表明,当改性戊二醛鞣剂用量为 2%、锆-铝-钛配合鞣剂用量为2%、阳离子油用量为0.4%时,复鞣效果和生态性能好,复鞣后的坯革也具有较好的耐热性能、感官性能和物理性能.这为皮革的生态设计提供了一种新思路.
Design and Optimization of Leather Chrome-free Retanning Process Based on Uniform Design
To improve the ecological performance of leather retanning process,using zirconium-aluminum-titanium tanned wet-white as raw material,taking the obtained leather's thermal shrinkage temperature,tear strength,sensory performance and COD content in retanning effluent as evaluation indicators,a chrome-free retanning process based on modified glutaraldehyde,zirconium-aluminum-titanium complex tanning agent and cationic oil was designed and optimized.The results showed that when the amount of modified glutaraldehyde tanning agent was 2%,the amount of zirconium-aluminum-titanium complex tanning agent was 2%,and the amount of cationic oil was 0.4%,the retanning effect and ecological performance were good,and the retanned crust leather also had good heat resistance,sensory performance and physical properties.It provides a new method for the eco-design of ecological leather.

leather engineeringchrome-free retanning processuniform designecological leathereco-design

孙辉永、林可心、温会涛、刘琳、吴渝玉、但卫华

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福建省皮革绿色设计与制造重点试验室,福建晋江 362271

中国轻工业制革绿色工程实验室,福建晋江 362271

兴业皮革科技股份有限公司国家企业技术中心,福建晋江 362261

四川大学制革清洁技术国家工程研究中心,四川成都 610065

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制革工程 无铬复鞣 均匀设计 生态皮革 生态设计

福建省科技计划项目福建省科技计划项目

2022H40142023L3053

2024

皮革与化工
中国皮革协会 全国皮革化工材料研究开发中心

皮革与化工

CSTPCD
影响因子:0.396
ISSN:1674-0939
年,卷(期):2024.41(1)
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