皮革与化工2024,Vol.41Issue(1) :15-17,22.

高效液相色谱法测定皮革中的双酚A、双酚F和双酚S

Determination of Bisphenol A,Bisphenol F and Bisphenol S in Leather by HPLC

肖湾 马红青 赵霞
皮革与化工2024,Vol.41Issue(1) :15-17,22.

高效液相色谱法测定皮革中的双酚A、双酚F和双酚S

Determination of Bisphenol A,Bisphenol F and Bisphenol S in Leather by HPLC

肖湾 1马红青 1赵霞1
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作者信息

  • 1. 上海市质量监督检验技术研究院,上海 201114
  • 折叠

摘要

建立了一种测定皮革中双酚A、双酚F和双酚S含量的分析方法.皮革样品经甲醇超声提取、旋转蒸发仪浓缩后,在 277 nm波长条件下,使用高效液相色谱仪进行分析,经二极管阵列器检测,甲醇-水溶液洗脱后,外标法进行定量.结果显示,双酚A、双酚F和双酚S在 1 mg·L-1~30 mg·L-1 的范围内线性相关系数均大于0.9995,检出限均小于 0.64 mg·kg-1,高、中、低三个水平加标回收率范围为 85.8%~97.1%,相对标准偏差为0.11%~2.22%,满足检测要求.

Abstract

An analytical method for the determination of bisphenol A,bisphenol F and bisphenol S in leather was established.Leather samples were extracted by methanol ultrasound,concentrated by rotary evaporator,analyzed by HPLC at 277 nm wavelength,detected by diode array,eluted by methanol-water solution,and quantified by external standard method.The results showed that the linear correlation coefficients of bisphenol A,bisphenol F and bisphenol S in the range of 1 mg·L-1~30 mg·L-1 were greater than 0.9995,the detection limits were less than 0.64 mg·kg-1,the recovery rates of spiked standard at high,middle and low levels were 85.8%~97.1%,and the relative standard deviations were 0.11%~2.22%,which met the detection requirements.

关键词

皮革/双酚A/双酚F/双酚S/测定

Key words

leather/bisphenol A/bisphenol F/bisphenol S/determination

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出版年

2024
皮革与化工
中国皮革协会 全国皮革化工材料研究开发中心

皮革与化工

CSTPCD
影响因子:0.396
ISSN:1674-0939
参考文献量6
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