首页|耐黄变非离子水性聚氨酯在皮革涂饰中应用

耐黄变非离子水性聚氨酯在皮革涂饰中应用

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聚氨酯涂饰材料在长时间受到紫外线或者热量影响下容易发生黄变,影响材料的美观和使用寿命.将紫外吸收剂UV-320和2-羟乙基二硫化物引入聚氨酯扩链中,制备耐黄变非离子水性聚氨酯,并应用于皮革喷涂,通过色差、稳定性、扫描电镜、X射线光谱等测试发现,在中涂工序加入50份数耐黄变非离子水性聚氨酯处理过的皮革的总色差△E为2.9,变色等级为1级,仅有很轻微色变.结合皮革拉伸强度和耐磨耗的基本性能指标,表明制备的耐黄变聚氨酯在保持皮革的力学性能、耐磨耗性能的同时,其耐黄变性能也大幅提高.
Yellowing-resistant Nonionic Waterborne Polyurethane for Leather Finishing Applications
Polyurethane finishing materials are susceptible to yellowing under the influence of ultraviolet light or heat for a long period of time,which affects the aesthetics and service life of the materials.The UV absorbent UV-320 and 2-hydroxyethyl disulfide were introduced into the polyurethane chain extension to prepare the yellow-resistant non-ionic waterborne polyurethane,and then applied to leather spraying.Through color difference,stability,scanning electron microscopy,X-ray spectroscopy and other tests,it was found that the total color difference △E of the leather treated with 50 parts of yellowing-resistant nonionic aqueous polyurethane in the step of mid-coating was 2.9,and the discoloration grade was 1 and only a very slight discoloration.Combined with the basic performance indexes of tensile strength and abrasion resistance of the leather,it shows that the prepared yellowing-resistant polyurethane can greatly improve the yellowing-resistant performance while maintaining the mechanical properties,abrasion-resistant performance of the leather.

nonionic waterborne polyurethaneleatherfinishing agentyellowing resistance

潘鑫蕊、张凯、张彤、鲁振威、丁燕波、翁永根、秦静、李国荣、曲家乐、于涵、段宝荣

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烟台大学化学化工学院皮革与蛋白质实验室,山东烟台 264005

德瑞(常州)特种材料有限公司,江苏常州 256401

晋江全杰生物科技有限公司,福建泉州 362200

滨州医学院药学院,山东烟台 264005

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非离子水性聚氨酯 皮革 涂饰剂 耐黄变

山东省中小企业提升项目山东省中小企业提升项目山东省自然基金面上项目

2022TSGC13542022TSGC2552ZR2023MB147

2024

皮革与化工
中国皮革协会 全国皮革化工材料研究开发中心

皮革与化工

CSTPCD
影响因子:0.396
ISSN:1674-0939
年,卷(期):2024.41(5)