首页|一种低共熔溶剂制备明胶基膜前驱液特性研究

一种低共熔溶剂制备明胶基膜前驱液特性研究

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以明胶为原料,经一种三水乙酸钠/尿素/水-低共熔溶剂(DES/H20)体系溶解后制备明胶基膜前驱液.与传统水体系溶解相比,DES/H20溶解的明胶暴露出更多活性基团,以碳二亚胺盐酸盐为交联剂可与聚乙烯醇形成更多酯键.对获得的明胶基膜前驱液进行表征,结果表明,DES/H20体系中DES含量为60%时(以DES/H2O溶液总质量为基准),所制备的明胶基膜前驱液的透光率为95.23%,粒径为1 524.0 nm,结晶温度为-31 ℃,当剪切速率为10 s-1时,黏度为449.07 mPa·s.表明此明胶基膜前驱液的交联作用较强,相容性较好,内部结构稳定,为制备具有较好物化性能的明胶基膜提供了新方法.
Study on the Characteristics of Gelatin-based Film Precursor So-lution Prepared Using a Deep Eutectic Solvent
Using gelatin as the raw material,a homogeneous solution was prepared by dissolving it in a ternary system of sodium acetate trihydrate/urea/water(DES/H2O).Compared to traditional water system,gelatin dissolved by DES/H2O can expose more active functional groups.Therefore,more ester bonds could be formed between gelatin and polyvinyl alcohol when using carbon diimide hydrochloride as a cross-linking agent.Results indicate that,when DES/H2O solvent contained 60%DES was used(based on the total mass of the DES/H2O solution),the prepared gelatin-based film precursor exhibited 95.23%of transmittance,1 524.0 nm of particle size,and-31 ℃ of crystallization temperature.At a shear rate of 10 s-1,its viscosity was 449.07 mPa·s.These findings suggest that the prepared gelatin-based precursor solution demonstrates strong cross-linking effect,good compatibility,and stable internal structure,providing a novel method for processing gelatin-based films with favorable physicochemical properties.

gelatindeep eutectic solventcrosslinkinggelatin-based filmprecursor solution

肖娅、吴婷、刘文涛、程飞、陈慧

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四川大学轻工科学与工程学院,四川成都610065

四川大学制革清洁技术国家工程实验室,四川成都610065

明胶 低共熔溶剂 交联 明胶基膜 前驱液

2024

皮革科学与工程
中国皮革协会 四川大学

皮革科学与工程

CSTPCD北大核心
影响因子:0.712
ISSN:1004-7964
年,卷(期):2024.34(5)