首页|钙钛矿太阳电池的界面钝化膜构建及钝化效果监测策略

钙钛矿太阳电池的界面钝化膜构建及钝化效果监测策略

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该文针对经典n-i-p结构的钙钛矿太阳电池中突出的TiO2/钙钛矿界面紫外不稳定问题,分析一步溶液法制备钝化膜的研究现状,并指出一步溶液法制备的钝化膜普遍存在太薄且裸漏的问题。最后,提出以廉价且全紫外光谱有效的无机盐屏障CsBr全面钝化TiO2 的研究策略,即通过超快结晶过程制备极薄且全覆盖的CsBr薄膜,形成微观尺度无机盐薄膜微结构调控的方法,此外,提出应用慢正电子湮没技术,定位监测钝化后钙钛矿的服役退化进程策略,这些对于实现TiO2/钙钛矿界面的紫外稳定化,具有理论和实践的双重指导价值。
Aiming at the prominent UV instability problem of TiO2/perovskite interface in classical n-i-p structure perovskite solar cells,the research status of one-step solution method preparation of passivation films is analyzed,and the paper points out that passivation films prepared by one-step solution method are generally too thin and exposed.Finally,a research strategy of comprehensively passivating TiO2 with a cheap and all-ultraviolet spectrally effective inorganic salt barrier CsBr is proposed.That is,an extremely thin and fully covered CsBr film is prepared through an ultra-fast crystallization process,forming a micro-scale inorganic salt film microstructure control method.In addition,a strategy of using slow positron annihilation technology to locate and monitor the service and degradation process of passivated perovskite is proposed.These have dual theoretical and practical guiding value for achieving ultraviolet stabilization of the TiO2/perovskite interface.

TiO2passivation filmperovskite solar cellsstrategyone-step solution method

党威武、胡艳凯

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陕西国防工业职业技术学院 智能制造学院,西安 710300

TiO2 钝化膜 钙钛矿太阳电池 策略 一步溶液法

2025

科技创新与应用
黑龙江省报刊出版有限公司 黑龙江省科协技术协会

科技创新与应用

影响因子:0.993
ISSN:2095-2945
年,卷(期):2025.15(1)