首页|热轧变形量对Al0.4Mg0.2Mn0.1Sn阳极合金电化学性能的影响

热轧变形量对Al0.4Mg0.2Mn0.1Sn阳极合金电化学性能的影响

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添加适量的Mg、Mn和Sn等合金元素制备了性能良好的Al0.4Mg0.2Mn0.1Sn阳极合金.采用析氢速率测试、电化学测试、恒流放电测试、显微组织和腐蚀形貌观察,分析不同热轧变形量对该阳极合金活性的影响.结果表明:适当的热轧变形量使阳极合金组织均匀,晶粒宽度变小,晶粒细化;适当的热轧变形量提升了该阳极合金的电化学性能,降低了腐蚀速率,改善了腐蚀形貌.Al0.4Mg0.2Mn0.1Sn阳极合金在60%热轧变形量下,自腐蚀速率最低,为0.167 mL(min·cm2);在60 mA/cm2电流密度下的放电电压达到1.27 V,最大功率密度为53.65 mW/cm2.
Effect of hot rolling reduction on the electrochemical properties of Al0.4Mg0.2Mn0.1Sn anode alloy
The high-performance Al0.4Mg0.2Mn0.1Sn anode alloy was prepared by adding appropriate amounts of alloying elements such as Mg,Mn,and Sn.The effects of dif-ferent hot rolling reductions on the anode alloy activity were analyzed by hydrogen evolution rate testing,electrochemical testing,and constant current discharge testing,microstructure and corrosion morphology observation.The results show that appropriate rolling reduction re-sults in uniform microstructure,reduces grain width,and refines grains.Appropriate hot rolling reduction improves the electrochemical performance of the anode alloy,reduces corro-sion rate,and improves corrosion morphology.At 60%hot rolling reduction,the self-corro-sion rate of Al0.4Mg0.2Mn0.1Sn is the lowest,which is 0.167 mL/(min·cm2).The dis-charge voltage of the alloy at 60 mA/cm2 reaches 1.27 V,and the maximum power density is 53.65 mW/cm2.

Al0.4Mg0.2Mn0.1Sn anode alloyhot rolling reductionhydrogen evolu-tionelectrochemical performance:discharge voltage

陈庆伦、何立子、李力爽、王美洋、王宇钦

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东北大学材料电磁加工重点实验室,辽宁 沈阳 110819

东北大学材料科学与工程学院,辽宁 沈阳 110819

Al0.4Mg0.2Mn0.1Sn阳极合金 热轧变形量 析氢 电化学性能:放电电压

国家重点研发计划"先进结构与复合材料"重点专项

2023YFB3710401

2024

轻合金加工技术
中国有色金属加工工业协会轻金属分会

轻合金加工技术

影响因子:0.31
ISSN:1007-7235
年,卷(期):2024.52(2)
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