Vegetable oil and mineral oil,as organic compounds with good vanadium removal effect of TiCl4,are widely used in titanium dioxide and titani-um sponge industry.In this paper,through a large number of experimental studies,7#,8#,9# mineral oil and imported vegetable oil can remove VOCl3 when the addition amount is lower than 0.07%.Moreover,the vanadium removal effect of vegetable oil is faster and better.However when applied to pro-duction,because the main component of vegetable oil is unsaturated fatty acid which contains oxygen element,the oxygen content of titanium sponge pro-duced is high,but titanium dioxide industry has no requirement for oxygen,so it is concluded that the effect of using vegetable oil is better in titanium di-oxide industry,since it has no requirement for oxygen.However,in the titanium sponge industry,oxygen and carbon as impurity elements,the require-ments for vanadium removal oil are stricter.Therefore,in the vanadium removal process of crude TiCl4,7 # mineral oil has better vanadium removal effect,with no more than 0.07%vanadium removal oil,the highest carbon distribution of C30 and the flash point at about 200℃.