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循环母液配料烧结处理赤泥提取氧化铝研究

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为解决碱石灰烧结法处理赤泥碳排放量高、生产成本高等问题,提出了以循环母液配料烧结处理赤泥提取氧化铝的创新工艺,系统研究了不同循环母液和纯碱配比对熟料烧结性能、浸出性能和浸出料浆沉降性能的影响,结果表明:以循环母液作为碱源配料烧结熟料主要物相组成为Na2O·Al2O3、2CaO·SiO2、2CaO·Fe2O3和CaO·TiO2;提高循环母液的配比可提高Al2O3和Na2O的浸出率;同时以循环母液为碱源配料使Fe2O3转化为2CaO·Fe2O3,从而改善了浸出料浆沉降性能.在以循环母液为碱源的条件下,熟料烧结过程二氧化碳排放量大幅度降低,熟料Al2O3和Na2O实际浸出率达到89%和96%以上,浸出料浆沉降速率可达10.55 m/h,泥层压缩率可达76%.
Research on extraction of alumina from red mud by sintering process with circulating spent liquor addition
In order to address the problems of high carbon emission and high production cost of lime-soda sintering process for treating red mud,a novel process to extract alumina from red mud by the sintering process with the addition of circulating spent liquor is proposed.Effects of different ratios of circu-lating spent liquor to sodium carbonate on the sintering properties and leaching properties of clinker as well as the settleability of leaching slurry are stud-ied.The results show that the main phases of the sintered clinker produced by using circulating spent liquor as alkali source are Na2O·Al2O3,2CaO·SiO2,2CaO·Fe2O3 and CaO·TiO2.Increasing the ratio of circulating spent liquor can improve the leaching rate of Al2O3 and Na2O.At the same time,the circulating spent liquor is used as alkali source to convert Fe2O3 into 2CaO·Fe2O3,and the settleability of leaching slurry can be im-proved as a result.Under the condition of using circulating spent liquor as alkali source,the carbon dioxide emissions during the sintering process of clink-er are significantly reduced,the actual leaching rates of clinker Al2O3 and Na2O are above 89%and 96%,the settling rate of the leaching slurry and the compressibility of the mud layer can reach 10.55 m/h and 76%,respectively.

red mudlow-carbon sinteringaluminaleachingsettlement

周庆华、廖鹏、李海东、王福平、潘晓林

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国家电投集团铝电投资有限公司,宁夏银川 750004

国家电投集团山西铝业有限公司,山西 忻州 034100

东北大学冶金学院,辽宁 沈阳 110819

赤泥 低碳烧结 氧化铝 浸出 沉降

2024

轻金属
沈阳铝镁设计研究院

轻金属

影响因子:0.358
ISSN:1002-1752
年,卷(期):2024.(8)