轻金属2024,Issue(8) :5-10.DOI:10.13662/j.cnki.qjs.2024.08.002

壳聚糖印迹树脂制备及吸附拜耳铝酸钠溶液钒的研究

Preparation of chitosan blotting resin and adsorption of Bayer sodium aluminate solution vanadium

杨超 张廷安 吕国志 刘平 王松
轻金属2024,Issue(8) :5-10.DOI:10.13662/j.cnki.qjs.2024.08.002

壳聚糖印迹树脂制备及吸附拜耳铝酸钠溶液钒的研究

Preparation of chitosan blotting resin and adsorption of Bayer sodium aluminate solution vanadium

杨超 1张廷安 2吕国志 1刘平 1王松1
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作者信息

  • 1. 东北大学冶金学院,辽宁沈阳 110000
  • 2. 东北大学冶金学院,辽宁沈阳 110000;中铝东南材料院(福建)科技有限公司,福建福州 350015
  • 折叠

摘要

氧化铝生产工艺中,拜耳铝酸钠溶液含有许多稀散的有价金属.如果将这些有价金属回收,可以减少资源浪费以及提高生产的经济效益.本文选用壳聚糖为原料,钒离子为模版离子,使用分子印迹技术成功制备了一种印迹树脂并枝接了季铵基团.研究了树脂对拜耳铝酸钠溶液中钒的吸附性能及机理.吸附实验表明在温度25℃、树脂用量10 g/L、吸附时间为40 min条件下,树脂吸附容量有3.23 mg/g.实验结果表明吸附过程符合准二级动力学模型,树脂可以选择性吸附钒离子.

Abstract

In the process of alumina production,Bayer sodium aluminate solution contains many dispersed valuable metals.If these valuable metals are re-cycled,it can reduce the waste of resources and improve the economic efficiency of production.In this paper,chitosan was used as raw material,vanadi-um ion as template ion,and a kind of imprinting resin was prepared by molecular imprinting technology and the quaternary amine group was grafted.The adsorption properties and mechanism of resin for vanadium in Bayer sodium aluminate solution were studied.The adsorption experiments showed that the adsorption capacity of the resin was 3.23 mg/g under the conditions of 25℃,10 g/L resin dosage and 40 min adsorption time.The experimental results showed that the adsorption process conformed to the quasi-second-order kinetic model,and the resin could selectively adsorb vanadium ions.

关键词

壳聚糖/钒离子/分子印迹/吸附机理

Key words

chitosan/vanadium ions/molecular blotting/adsorption mechanism

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基金项目

国家自然科学基金(ZX20230386)

东北大学交叉融合协同发展项目(N2225013)

江西省双千计划(S2021DQKJ2198)

出版年

2024
轻金属
沈阳铝镁设计研究院

轻金属

影响因子:0.358
ISSN:1002-1752
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