全面腐蚀控制2024,Vol.38Issue(1) :115-118.DOI:10.13726/j.cnki.11-2706/tq.2024.01.115.04

CO2-O2环境中油井管钢的腐蚀研究

Corrosion of Oil Well Tube Steel in CO2-O2 Environment

张雅妮 樊冰 王思敏
全面腐蚀控制2024,Vol.38Issue(1) :115-118.DOI:10.13726/j.cnki.11-2706/tq.2024.01.115.04

CO2-O2环境中油井管钢的腐蚀研究

Corrosion of Oil Well Tube Steel in CO2-O2 Environment

张雅妮 1樊冰 1王思敏1
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作者信息

  • 1. 西安石油大学 材料科学与工程学院,陕西 西安 710065
  • 折叠

摘要

油气田开采过程中井下环境复杂,影响因素较多,CO2-O2共存环境对油井管钢造成严重腐蚀且目前研究较少,所以分析CO2-O2环境中油井管钢的腐蚀行为很有必要.本文通过对CO2-O2共存环境中油井管钢腐蚀机制的研究,结果如下:(1)CO2腐蚀在早期成膜后速度下降到很低,CO2-O2共存环境下腐蚀速率一直保持较高.(2)单一CO2环境腐蚀后钢表面生成致密FeCO3膜,保护基体防止继续腐蚀,而在CO2-O2共存环境下,腐蚀产物主要为FeCO3和Fe氧化物,其中Fe氧化物使得FeCO3晶体间的附着力降低,膜层疏松多孔,从而促进腐蚀.(3)温度升高使氧的传质速度加快,腐蚀产物中保护性较差的Fe氧化物增多,导致腐蚀速率急剧增加.

Abstract

In the process of oil and gas field exploitation,the underground environment is complex and there are many influencing factors.CO2-O2 coexistence environment causes serious corrosion of oil well pipe steel,and there are few studies at present,so it is necessary to analyze the corrosion behavior of oil well pipe steel in CO2-O2 environment.In this paper,the corrosion mechanism of oil well pipe steel in CO2-O2 coexistence environment is studied,and the results are as follows:(1)CO2 corrosion rate drops to a very low after the early film formation,and the corrosion rate remains high in CO2-O2 coexistence environment.(2)After corrosion in a single CO2 environment,dense FeCO3 film is formed on the steel surface to protect the matrix from further corrosion,while in the CO2-O2 environment,the corrosion products are mainly FeCO3 and Fe oxides,among which Fe oxides reduce the adhesion between FeCO3 crystals and make the film loose and porous,thus promoting corrosion.(3)The temperature increase accelerates the mass transfer rate of oxygen,and the Fe oxides in the corrosion products with poor protection to the matrix increase,resulting in a sharp increase in the corrosion rate.

关键词

CO2/O2腐蚀/腐蚀机制/腐蚀影响因素

Key words

CO2/O2 corrosion/corrosion mechanism/corrosion influencing factors

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基金项目

陕西省自然科学基础研究计划(2022JM-269)

出版年

2024
全面腐蚀控制
中国工业防腐蚀技术协会

全面腐蚀控制

影响因子:0.278
ISSN:1008-7818
参考文献量20
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