首页|ZAlSi7Mg1A铸造铝合金本色导电氧化工艺研究

ZAlSi7Mg1A铸造铝合金本色导电氧化工艺研究

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ZAlSi7Mg1A(ZL114A)铸造铝合金是一种应用较为广泛的铸造Al-Si合金材料,它适用于航空、航天及兵工等领域.本文以ZAlSi7Mg1A(ZL114A)铸造铝合金本色导电氧化工艺为研究对象,针对前处理及反应过程的优化进行了大量实验,经过碱性点滴试验、硫酸铜点滴试验和盐雾试验,最终获得了有较好耐磨性及耐蚀性的本色导电氧化膜,同时还探究了影响ZAlSi7Mg1A(ZL114A)铸造铝合金本色导电氧化成膜及耐蚀性的条件.讨论了温度、气管开度、去离子水、磷酸、铬酸酐、氟化钠、重复氧化和老化对成膜及耐蚀性的影响.并且对比了较成熟的导电氧化工艺(铬酸盐成膜)膜层耐蚀性.分析后得出以下结论:(1)本色导电氧化膜发灰及膜层性能不佳主要是出光步骤的问题;(2)在28~30℃条件下,一定浓度的磷酸-铬酸盐溶液中,pH为1.8~2.1,反应时间为4min时,耐蚀性达到最佳.
The Exploration of The Conductive Oxidation Process for Casting Aluminum Alloy ZAlSi7Mg1A
ZAlSi7Mg1A(ZL114A)cast aluminum alloy is a widely used cast Al-Si alloy material,which is suitable for aviation,aerospace and weapons industry and other fields.This study focuses on investigating the Natural color conductive anodizing process of ZAlSi7Mg1A(ZL114A)cast aluminum alloy and conducts numerous experiments to optimize pretreatment and reaction processes.After alkaline drop test,copper sulfate drop test and salt spray test,the Natural color conductive anodizing film with good wear resistance and corrosion resistance was finally obtained.At the same time,the conditions affecting the formation and corrosion resistance of ZAlSi7Mg1A(ZL114A)cast aluminum alloy Natural color conductive anodized were also explored.The effects of temperature,tracheal opening,deionized water,phosphoric acid,chromate anhydride,sodium fluoride,repeated oxidation and aging on the formation and corrosion resistance were discussed.And the corrosion resistance of the more mature conductive oxidation process(chromate film)was compared.The following conclusions were drawn after analysis:(1)The ash and poor performance of the Natural color conductive anodized film are mainly the problem of the light extraction step;(2)Under the condition of 28~30° C,a certain concentration of phosphate-chromate solution,pH is 1.8~2.1,and the reaction time is 4min,the corrosion resistance reaches the best.

casting aluminum alloynatural color conductive anodizingcorrosion resistance

张博宸、武丽茹、张怡辉

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河北燕兴机械有限公司,河北张家口 075000

铸造铝合金 本色导电氧化 耐蚀性

2024

全面腐蚀控制
中国工业防腐蚀技术协会

全面腐蚀控制

影响因子:0.278
ISSN:1008-7818
年,卷(期):2024.38(7)
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