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药用工业大麻茎叶中10种重金属含量测定

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建立了药用工业大麻茎叶中10种重金属(Cu、Zn、Mn、Fe、Ni、Cd、Pb、Cr、Hg、As)含量的火焰原子吸收分光光度法和电感耦合等离子体质谱检测方法,并对重金属的可能来源进行分析.结果表明,检测方法准确、可靠,10种重金属元素在各自范围内线性关系良好(R2≥0.999).药用工业大麻中重金属(Pb、As、Cd、Hg、Cu)质量分数均符合《中国药典》(2020)对药材及饮片(植物类)中重金属限量标准,但Cu、Cr和Hg元素的质量分数超过其他不同国家和组织的最小重金属限量标准,超标率分别为63.64%,45.45%,9.09%.药用工业大麻茎叶中重金属主要来源为环境因素,其次为生产种植因素,以及多种残留物产生的多重累积和协同效应.
Determination of ten heavy metals in the stems and leaves of medicinal industry hemp
A flame atomic absorption spectrophotometry or inductively coupled plasma mass spectrometry method was established to detect the content of ten heavy metals(Cu,Zn,Mn,Fe,Ni,Cd,Pb,Cr,Hg,As)in the stems and leaves of medicinal industrial hemp,and to analyze the possible sources of heavy metals.The results showed that the detection method was accurate and reliable,and the linear relationship between the ten heavy metal elements was good within their respective ranges(R2 ≥ 0.999).The mass concentrations of heavy metals(Pb,As,Cd,Hg,Cu)in the medicinal industry of cannabis all comply with the heavy metal limit standards for medicinal materials and herbal(plant)in the"Chinese Pharmacopoeia"(2020).However,the mass concentrations of Cu,Cr,and Hg elements exceed the minimum heavy metal limit standards of other countries and organizations,with exceeding rates of 63.64%,45.45%,and 9.09%,respectively.The main sources of heavy metals in the stems and leaves of medicinal hemp industry are environmental factors,followed by production and planting factors,as well as the multiple accumulation and synergistic effects of various residues.

medicinal industrial hempheavy metalsFAASICP-MSmass fraction measurementsource analysis

徐栖笛、孙百超、初美凤、赵福全、秦世丽、高立娣

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齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔 161006

国家市场监管技术创新中心(工业大麻),黑龙江齐齐哈尔 161006

药用工业大麻 重金属 FAAS ICP-MS 质量分数测定 来源分析

2022年度黑龙江省省属高等学校基本科研业务费科研项目齐齐哈尔大学研究生创新科研项目基金

145209501QUZLTS_CX2023030

2024

齐齐哈尔大学学报(自然科学版)
齐齐哈尔大学

齐齐哈尔大学学报(自然科学版)

影响因子:0.182
ISSN:1007-984X
年,卷(期):2024.40(5)