染料与染色2024,Vol.61Issue(3) :20-22,61.

3-甲基-4-氨基-N-乙基-N-(2-羟基乙基)-苯胺合成工艺

Synthesis of 3-Methyl-4-Amino-N-Ethyl-N-(2-Hydroxyethyl)-Aniline

陈思宇 高志成 史美慧 刘红翼 王雪梅 单体育
染料与染色2024,Vol.61Issue(3) :20-22,61.

3-甲基-4-氨基-N-乙基-N-(2-羟基乙基)-苯胺合成工艺

Synthesis of 3-Methyl-4-Amino-N-Ethyl-N-(2-Hydroxyethyl)-Aniline

陈思宇 1高志成 1史美慧 1刘红翼 1王雪梅 1单体育1
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作者信息

  • 1. 沈阳化工研究院有限公司,沈阳 110021
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摘要

本文合成了 3-甲基-4 氨基-N-乙基-N-(2-羟基乙基)-苯胺硫酸盐(CD-4)显影剂,并对其合成工艺进行了研究.结果表明,Pt/C作为催化剂、甲醇作为加氢溶剂、温度 60℃、压力 0.8~1.5 MPa为最佳工艺条件.在该条件下,加氢转化率达 100%.硫酸中和度 105%时,粗品收率为 76%.使用活性炭 1%用量,水(33%)/乙醇(67%)作为重结晶溶剂进行产品精制可制得合格的目标产品.

Abstract

A developing agent,3-Methyl-4-amino-N-ethyl-N-(2-hydroxyethyl)-aniline sulfate(CD-4),was synthesized;its synthesis process was studied.The results showed that the optimum process conditions were Pt/C as catalyst,methanol as solvent,temperature 60℃,pressure 0.8~1.5 MPa.In the conditions,the conversion rate of hydrogenation was 100%.When the neutraliza-tion degree of sulfuric acid was 105%,the yield of crude product was 76%.Using 1%of activated carbon,water(33%)/ethanol(67%)as recrystallization solvent to refine the product,the target product with qualified color could be prepared.

关键词

显影剂/CD-4/催化加氢/工艺

Key words

developing agent/CD-4/catalytic hydrogenation/process

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出版年

2024
染料与染色
沈阳化工研究院有限公司

染料与染色

影响因子:0.273
ISSN:1672-1179
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