首页|全TOPCon电池正面多晶硅层硼掺杂工艺

全TOPCon电池正面多晶硅层硼掺杂工艺

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为提升隧穿氧化层钝化接触(TOPCon)电池光电转换效率,本文通过高温扩散在n型TOPCon电池正面制作p型隧穿氧化层钝化接触结构,提升发射极钝化性能,减少正面金属复合.本文研究了不同沉积时间、推进温度、推进时间等工艺参数对实验样品钝化性能及掺杂曲线的影响.实验结果表明,当沉积时间为1 500 s,推进温度为920 ℃,推进时间为20 min时,掺硼多晶硅层可获得较优的钝化性能及掺杂浓度,其中样品多晶硅层硼掺杂浓度达到1.40 × 1020 cm-3,隐开路电压(iV)大于720.0 mV.依据该参数制备的TOPCon电池光电转换效率可达23.89%,对应的短路电流密度为39.36 mA/cm2,开路电压(Voc)达到726.4 mV,填充因子(FF)为83.54%.
Boron Doping Technology for the Front Polysilicon Layer of Full TOPCon Cells
In order to improve the efficiency of tunneling oxide passivated contact(TOPCon)cells,a p-type tunneling oxide passivation contact structure was fabricated on the front of N-type TOPCon cells through high-temperature diffusion,improving the emitter passivation performance and reducing front metal recombination.The effects of different deposition time,drive-in temperature,drive-in time and other process parameters on the passivation performance and doping curve of experimental samples were investigated.The experimental results show that when the deposition time is 1 500 s,the drive-in temperature is 920 ℃,and the drive-in time is 20 min,the boron doped polysilicon layer can achieve better passivation performance and boron doping concentration,with the doping concentration of sample poly crystalline silicon layer reaching 1.40 x 1020 cm-3.The implied open circuit voltage(iV0c)is greater than 720.0 mV.The photoelectric conversion efficiency of TOPCon cells prepared based on this parameter can reach 23.89%,corresponding to a short-circuit current density of 39.36 mA/cm2,the open circuit voltage(Voc)is 726.4 mV,and the fill factor(FF)is 83.54%

TOPCon celltunnel oxide passivation contactboron diffusionpassivationcurrent densityphotoelectric conversion efficiency

张博、宋志成、倪玉凤、魏凯峰

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青海黄河上游水电开发有限责任公司西安太阳能电力分公司,西安 710000

西安电子科技大学微电子学院,宽禁带半导体材料与器件教育部重点实验室,西安 710071

TOPCon电池 钝化接触 硼扩散 钝化 电流密度 光电转换效率

2024

人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
年,卷(期):2024.53(2)
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