首页|掺铈Cs2BaBr4晶体的生长和闪烁性能研究

掺铈Cs2BaBr4晶体的生长和闪烁性能研究

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以高纯度BaBr2、CsBr、CeBr3为原料,采用高温固相反应法合成了 Cs2BaBr4∶1%Ce3+多晶料,并通过坩埚下降法生长了 Cs2BaBr4∶1%Ce3+晶体。将晶体切割研磨抛光后得到不同厚度的Cs2BaBr4:1%Ce3+晶片。对晶体进行了物相分析,XRD图谱表明晶体为一致熔融物,且无相变。研究了晶体的闪烁性能,测试了光学透射率、光致发光、X射线激发发光、多通道gamma能谱、衰减时间。与LaBr3晶体对比,分析了晶体的吸湿性。结果表明,晶体的光学透过率接近80%,在一定波段的紫外光及X射线的激发下,晶体在349与372 nm波长有发射峰。137Cs源伽马射线的激发下,能量分辨率为11%,在紫外激发下,晶体衰减时间为21。9 ns。晶体的吸湿性比LaBr3晶体有大幅改善。
Growth and Scintillation Properties of Cerium-Doped Cs2BaBr4 Crystal
Using BaBr2,CsBr,and CeBr3 with high-purity as raw materials,the Cs2BaBr4∶1%Ce3+polycrystalline powders were synthesized by solid-state reaction method.The crystal of Cs2 BaBr4∶1%Ce3+was grown by Bridgman method.The wafer of Cs2BaBr4:1%Ce3+with different thickness were obtained by incising,grinding and polishing process.The phase of the crystal was analyzed,and XRD patterns show that the crystal is a uniformly molten substance with no phase transition.The scintillation performance of the crystal was studied,which the optical transmittance,photo luminescence,X-ray induced luminescence,multi-channel gamma energy spectrum and decay time were measured.Compared with the crystal of LaBr3,the hygroscopicity of the crystal was analyzed.The results show that the optical transmittance of crystal is close to 80%,and under the excitation of ultraviolet light and X-rays in a certain band,the crystal exhibits emission peaks at wavelengths around 349 and 372 nm.The energy resolution under the excitation of gamma rays of 137 Cs is estimated to be 11%.The decay time under the excitation of UV light is fitted to be 21.9 ns.The hygroscopicity of the crystal is much better than that of LaBr3 crystal.

Cs2BaBr4∶1%Ce3+crystalBridgman methodphoto luminescenceX-ray induced luminescencedecay timehygroscopicit

殷洁、张小强、陈灿、潘建国

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湖南化工职业技术学院,株洲 412000

宁波大学材料科学与化学工程学院,浙江省光电探测材料及器件重点实验室,宁波 315211

Cs2BaBr4∶1%Ce3+晶体 坩埚下降法 光致发光 X射线激发发光 衰减时间 吸湿性

湖南省教育厅科研项目(2021)

21C1116

2024

人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
年,卷(期):2024.53(5)
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