人工晶体学报2024,Vol.53Issue(11) :1892-1900.

不同掺杂浓度Er∶Lu2O3透明陶瓷的制备与性能研究

Fabrication and Properties of Er∶Lu2O3 Transparent Ceramics with Different Doping Concentrations

刘子玉 郑雯雯 冯亚刚 叶君豪 刘鹏 杨现锋 李江
人工晶体学报2024,Vol.53Issue(11) :1892-1900.

不同掺杂浓度Er∶Lu2O3透明陶瓷的制备与性能研究

Fabrication and Properties of Er∶Lu2O3 Transparent Ceramics with Different Doping Concentrations

刘子玉 1郑雯雯 2冯亚刚 3叶君豪 4刘鹏 2杨现锋 2李江4
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作者信息

  • 1. 长沙理工大学材料科学与工程学院,长沙 410004;中国科学院上海硅酸盐研究所透明陶瓷研究中心,上海 201899
  • 2. 长沙理工大学材料科学与工程学院,长沙 410004
  • 3. 河南工业大学材料科学与工程学院,郑州 450001
  • 4. 中国科学院上海硅酸盐研究所透明陶瓷研究中心,上海 201899;中国科学院大学材料与光电中心,北京 100049
  • 折叠

摘要

Er∶Lu2O3透明陶瓷具有高热导率、高抗热震性能、良好的光谱特性和低制备温度等优势,是实现近、中红外波段高效率、高功率激光输出的候选固态增益介质之一.针对Er∶Lu2O3透明陶瓷的应用激光波段,探究Er3+掺杂浓度对陶瓷制备和性能的影响,对实现高品质Er∶Lu2O3陶瓷的研制非常关键.本文以共沉淀法合成Er∶Lu2O3纳米粉体,采用真空预烧结合热等静压(HIP)烧结工艺制备出Er∶Lu2O3透明陶瓷.研究表明,1 100℃煅烧的Er∶Lu2O3纳米粉体物相与立方相Lu2O3 一致,10%Er掺杂浓度(原子数分数)粉体分散性更好.经过1 500℃预烧所得的0.3%和10%(原子数分数)Er∶Lu2O3陶瓷的平均晶粒尺寸分别为0.86和0.87 μm,相对密度分别为95.1%和96.2%.对应预烧陶瓷经过1 750 ℃ HIP后,在2 400 nm处直线透过率分别为71.6%和78.0%(厚度2.9 mm),其中,0.3%Er∶Lu2O3陶瓷残留较多气孔,在短波范围直线透过率锐降.计算了 Er∶Lu2O3透明陶瓷的吸收和发射光谱,0.3%Er∶Lu2O3陶瓷在1.55 μm波段具有更高的吸收、发射截面.

Abstract

Er∶Lu2 O3 transparent ceramics are one of the candidate solid-state gain media for high efficiency and high power laser in the near and mid-infrared bands due to the advantages of high thermal conductivity,high thermal shock resistance,good spectral properties and low preparation temperature.Exploring the influence of Er3+doping concentration(atomic number fraction)on the preparation and properties of Er∶Lu2 O3 transparent ceramics for the related laser application is crucial for achieving high-quality Er∶Lu2O3 ceramics.In this paper,Er∶Lu2O3 transparent ceramics were fabricated using vacuum pre-sintering combined with hot isostatic pressing(HIP)post-treatment from the nano-powders synthesized by the coprecipitation method.The results show that the phases of all Er∶Lu2O3 nano-powders calcined at 1 100℃with different Er3+concentrations are almost consistent with that of the pure cubic Lu2O3 and the 10%Er∶Lu2O3 nano-powder shows better dispersibility.The average grain sizes of 0.3%and 10%Er∶Lu2O3 ceramics pre-sintered at 1 500 ℃ are 0.86 and 0.87 μm with the relative densities of 95.1%and 96.2%,respectively.The corresponding pre-sintered ceramics were HIP-ed at 1 750 ℃ show the in-line transmittance of 71.6%and 78.0%(thickness 2.9 mm)at 2 400 nm,respectively.Especially,the in-line transmittance of the 0.3%Er∶Lu2O3 ceramics sharply decreases in the short wave range due to the numerous remained residual pores.The absorption and emission spectra of 0.3%and 10%Er∶Lu2O3 transparent ceramics were calculated.0.3%Er∶Lu2O3 ceramics possesses higher absorption and emission cross-sections around the band centered at 1.55 μm.

关键词

Er∶Lu2O3/纳米粉体/两步烧结/透明陶瓷/微观结构/光学特性

Key words

Er∶Lu2O3/nano-powder/two-step sintering/transparent ceramics/microstructure/optical property

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出版年

2024
人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
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