首页|稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究

稀土离子过量掺杂TSAG及YAG/TSAG复合结构透明陶瓷的制备与性能研究

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本文研究了 Nd3+、Ho3+、Dy3+和Ce3+稀土离子过量掺杂对TSAG陶瓷制备及相关性能的影响,结果表明:稀土离子过量掺杂对TSAG陶瓷的微观缺陷和透过率产生了一定的影响,晶粒表面存在非二次相的少量细小颗粒,从而导致陶瓷样品透过率下降.在相同测试波长下,稀土离子过量掺杂TSAG陶瓷的Verdet常数优于纯相TSAG陶瓷.此外,本文还探索了 YAG/TSAG基双层复合结构陶瓷,成功制备了YAG/TSAG及YAG/2.0%Ce∶TSAG双层复合结构陶瓷,双层结构接触面形成了亚微米级厚度的过渡层,YAG/TSAG陶瓷在波长1 064 nm处的透过率达到71.0%,YAG/TSAG基复合陶瓷的成功制备,拓宽了 TSAG材料在高功率激光器上的应用前景.
Preparation and Properties of Rare Earth Ion Over-Doped TSAG and YAG/TSAG Composite Structural Transparent Ceramics
;In this paper,the effects of over-doping of Nd3+,Ho3+,Dy3+and Ce3+rare earth ions on the preparation and related properties of TSAG ceramics were investigated,and the results show that over-doping of rare earth ions has a certain effect on the micro-defects and transmittance of TSAG ceramics.The existence of a small number of fine particles which are not in the secondary phase on the grain surface,led to the decrease of the transmittance of the ceramic samples.The Verdet constant of rare earth ion over-doped TSAG ceramics is better than that of pure phase TSAG ceramics at the same test wavelength.In addition,YAG/TSAG-based bilayer composite structural ceramics were explored.The YAG/TSAG and YAG/2.0%Ce∶TSAG bilayer composite structural ceramics were successfully prepared,with sub-micron thickness transition layer formed on the contact surface,and the transmittance of the YAG/TSAG ceramics at 1 064 nm reaches 71.0%.The successful preparation of YAG/TSAG-based composite ceramics broadens the application prospects of TSAG materials in high-power lasers.

rare earth ionover-dopingtransparent ceramicsVerdet constantbilayer composite structural ceramicsmicrostructureoptical property

冯桂青、徐刘伟、袁亚舟、郑熠、黄鑫、陈旻、王帅华、吴少凡

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中国科学院福建物质结构研究所,福州 350002

中国福建光电信息与技术创新实验室,福州 350108

福建师范大学化学与材料学院,福州 350117

稀土离子 过量掺杂 透明陶瓷 Verdet常数 双层复合结构陶瓷 微观结构 光学性能

2024

人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
年,卷(期):2024.53(11)