首页|无铅0.96KNNTSx-0.04BNKZ透明压电陶瓷的制备及其光电性能研究

无铅0.96KNNTSx-0.04BNKZ透明压电陶瓷的制备及其光电性能研究

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本文制备了0.96(K0.48 Na0.52)(Nb0.95-xTa0.05 Sbx)O3-0.04Bi0.5(Na0.82 K0.18)0 5ZrO3(即0.96KNNTSx-0.04BNKZ,x=0.03,0.04,0.06,0.07)无铅透明压电陶瓷,并探讨了不同Sb掺杂量对陶瓷压电性能和光学透明度的影响.结果表明,所有陶瓷样品均为钙钛矿结构,且Sb掺杂显著改善了陶瓷的压电性能和透明度.尤其在x=0.04时,样品的压电系数达到240 pC/N,光学透过率在波长780 nm处达到31.5%.该研究表明,通过成分设计调控,KNN基无铅陶瓷能够同时实现较好的透明度和高的压电性能,在光声成像和透明换能器等领域具有重要应用潜力.
Preparation and Opto-Electric Properties of Lead-Free 0.96KNNTSx-0.04BNKZ Transparent Piezoelectric Ceramics
In this study,0.96(K0.48Na0.52)(Nb0.95-xTa0.05Sbv)O3-0.04Bi0.5(Na0.82K0.18)0.5ZrO3(0.96KNNTSx-0.04BNKZ,x=0.03,0.04,0.06,0.07)lead-free transparent piezoelectric ceramics were prepared,and the effects of Sb doping levels on their piezoelectric properties and optical transparency were examined.All samples exhibit a perovskite structure.With increasing Sb content,both piezoelectric performance and transparency improve.Notably,at x=0.04,the piezoelectric coefficient reaches 240 pC/N,with an optical transmittance of 31.5%at 780 nm.This study demonstrates that compositional design can achieve enhanced transparency and high piezoelectric performance in KNN-based lead-free ceramics,offering significant potential for applications in optoacoustic imaging and transparent transducers.

KNNtransparent ceramicspiezoelectricdomain structurelead-freecompositional tuning

王亚祺、付大石、王亚男、秦亚琳、张永成

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青岛大学物理科学学院,青岛 266000

KNN 透明陶瓷 压电 电畴结构 无铅 成分调控

2024

人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
年,卷(期):2024.53(11)