首页|Lu2O3基激光透明陶瓷的研究进展

Lu2O3基激光透明陶瓷的研究进展

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倍半氧化物Lu2O3因具有优异的热力学性能、低声子能量和强晶体场等特点,成为近红外和中红外光谱(1~3 µm)范围内的宽带发射高功率激光基体材料的优秀候选者之一,近年来受到人们的广泛关注.Lu2O3的熔点高达2 450 ℃,单晶生长极为困难,限制了其应用发展.但Lu2O3属于立方晶系,具有光学各向同性,因此制备Lu2O3基透明陶瓷成为一种可行的方案.透明陶瓷可以在较低的温度下(晶体熔点的60%~80%)烧结制备大尺寸样品,同时烧结周期相较于晶体生长周期大幅缩减,更有利于大量生产,因此制备Lu2O3基透明陶瓷作为新型激光介质材料更有潜力被广泛应用于科学研究、工业生产和日常生活.本文总结了基于稀土离子(Nd3+、Er3+、Yb3+、Tm3+、Ho3+)掺杂的Lu2O3基激光透明陶瓷的制备工艺及其性能参数的最新研究进展.未来,Lu2O3基激光陶瓷的开发将聚焦在大尺寸、高功率输出、低散射特性、高热稳定性、复合结构设计等方面以推动高性能固体激光器的发展.
Research Progress on Lu2O3 Based Laser Transparent Ceramics
Sesquioxide Lu2O3 has excellent thermodynamic properties,low phonon energy and strong crystal field characteristics,making it one of the excellent candidates for wideband high-power laser matrix materials in the near-infrared and mid-infrared spectra(1~3 µm),and attracting widespread attention in recent years.Since Lu2O3 has a melting point of up to 2 45O ℃,growing single crystal is extremely difficult,limiting its application development.However,Lu2O3 belongs to the cubic crystal system and is optically isotropic,making Lu2O3-based transparent ceramics a viable option.Compared to single crystal,transparent ceramics can be sintered at lower temperatures(60%~80%of the melting point of crystals)to prepare large-size samples,while the sintering cycle is greatly reduced and more conducive to mass production,so the preparation of Lu2O3-based transparent ceramics as a new type of laser material has the potential for a wider range of applications in scientific research,industrial production and daily life.In this paper,the preparation technology and properties of Lu2O3-based laser transparent ceramics doped with rare earth ions(Nd3+,Er3+,Yb3+,Tm3+,Ho3+)are reviewed.In the future,the development of half-oxide Lu2O3-based laser ceramics will be focused on large size,high power output,low scattering characteristics,high thermal stability,and composite structure design to promote the development of high-performance solid-state lasers.

transparent ceramicsLu2O3laser ceramicssesquioxidesolid-state laserlaser gain medium

赵文海、陶世旭、童思意、唐健、左传东、曹永革、麻朝阳

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松山湖材料实验室,东莞 523808

中科皓烨(东莞)材料科技有限责任公司,东莞 523808

中国科学院物理研究所,北京 100190

透明陶瓷 Lu2O3 激光陶瓷 倍半氧化物 固体激光器 激光增益介质

2024

人工晶体学报
中材人工晶体研究院

人工晶体学报

CSTPCD北大核心
影响因子:0.554
ISSN:1000-985X
年,卷(期):2024.53(12)