首页|基于邻苯二甲腈树脂的高耐热电子封装模塑料的制备

基于邻苯二甲腈树脂的高耐热电子封装模塑料的制备

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以4-氨基苯氧基邻苯二甲腈(APN)和多官能环氧树脂为基体树脂,2-甲基咪唑为固化促进剂,配合无机填料等助剂,制备了电子封装模塑料(AEM).对AEM的热性能、力学性能、耐老化性能、介电性能和阻燃性能进行了测试,并与商用环氧模塑料(EMC)作了对比.AEM的成型工艺与EMC相容.与商用EMC固化物相比,固化后的AEM表现出优异的高温稳定性(Tg>230℃)和耐高温老化性能(200℃,500 h).此外,AEM固化物具有较低的介电常数和介电损耗,表现出良好的电绝缘性.值得注意的是,AEM固化物可以在不添加阻燃剂的情况下具有阻燃效果,且能达到UL-94V-0 级别.该模塑料在功率器件封装领域具有良好的应用前景.
Preparation of high heat-resistance electronic packaging molding compound based on phthalonitrile resin
The electronic packaging molding compound(AEM)was prepared with 4-aminophenoxy-o-phthalonitrile(APN)and multifunctional epoxy resin as matrix resins,2-methylimidazole as curing accelerator,and inorganic fillers.The thermal properties,mechanical properties,aging resistance,dielectric properties and flame retardancy of AEM were tested and compared with those of commercial epoxy molding compound(EMC).The molding process of AEM was compatible with that of EMC.The cured AEM exhibited excellent high temperature stability(Tg>230 ℃)and high temperature aging resistance(200 ° C,500 h)compared with the cured EMC.In addition,the cured AEM had low dielectric constant and dielectric loss,exhibiting a good electrical insulation.It was important to note that the cured AEM exhibited a good flame-retardant performance without the addition of flame retardant,and could reach V-0 rating in UL-94 testing.The molding compound has a good application prospect in the field of power device packaging.

phthalonitrileepoxy resinmolding compoundheat resistantflame retardantelectronic packaging

黄家腾、朱飞宇、包颖、费小马、魏玮

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江南大学化学与材料工程学院,江苏 无锡 214122

无锡创达新材料股份有限公司,江苏 无锡 214028

邻苯二甲腈 环氧树脂 模塑料 耐热 阻燃 电子封装

2018年江苏省产学研合作项目

BY2018041

2024

热固性树脂
天津市合成材料工业研究所

热固性树脂

CSTPCD
影响因子:0.363
ISSN:1002-7432
年,卷(期):2024.39(4)