首页|硼酸酯润滑油添加剂的设计、制备及在齿轮油中的应用研究

硼酸酯润滑油添加剂的设计、制备及在齿轮油中的应用研究

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为了进一步提高齿轮油CKD 320的摩擦学性能,设计、制备了 3种带有不同官能团的绿色环保含硼添加剂:饱和碳链的硬脂酸二乙醇酰胺硼酸酯(C18)、带有C=C双键的油酸二乙醇酰胺硼酸酯(C18∶1)和带有极性基团羟基和双键的蓖麻油酸二乙醇酰胺硼酸酯(C18∶1OH).通过调控硼酸酯润滑油添加剂的极性,研究硼酸酷的极性对齿轮油CKD 320摩擦学性能的影响.结果表明:3种硼酸酯添加剂可以在不改变齿轮油CKD 320理化性能的情况下,提高齿轮油的减摩和抗磨性能以及承载能力,硼酸酯的极性越强,越易在摩擦表面吸附,抗磨性越高.
Design and Preparation of Borate Ester Lubricating Additives and Study on Their Application in Gear Oil
In the paper,to further improve the tribological properties of gear oil CKD 320,three green and environmentally friendly boron-containing additives with different functional groups,i.e.carbon-chain saturated stearic acid diethano-lamide borate(C18),oleic acid diethanolamide borate with C=C double bonds(C18∶1)and ricinoleic acid diethanolamide borate with polar hydroxyl groups and double bonds(C18∶1OH),were designed and prepared.By adjusting the polarity of borate ester lubricant additives,the effect of borate ester polarity on the tribological properties of gear oil CKD 320 was stud-ied.The results show that three kinds of borate ester additives can improve the friction reduction and anti-wear properties and load-carrying capacity of gear oil CKD 320 without changing the physical and chemical properties.The stronger the po-larity of borate ester,the easier it is to absorb on the friction surface,and the higher the wear resistance.

boratedifferent functional groupspolarityadditivegear oil,tribological property

杨汐、杨广彬、张晟卯、张玉娟、张平余

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河南大学纳米材料工程研究中心,河南开封 475004

硼酸酯 不同官能团 极性 添加剂 齿轮油 摩擦学性能

清华大学高端装备界面科学与技术全国重点实验室开放基金

SKLTKF21B06

2024

润滑油
中国石油润滑油公司

润滑油

影响因子:0.392
ISSN:1002-3119
年,卷(期):2024.39(2)
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