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新疆高碱高氯煤燃烧条件下细颗粒物生成特性研究

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为比较新疆地区典型高碱煤和高氯煤在燃烧条件下颗粒物生成特性,采用三段式高温沉降炉系统开展在空气气氛下燃烧准东煤和沙尔湖煤的实验,分析燃烧后颗粒物特征.采用Dekati低压撞击器(Dekati low pressure impactor+,DLPI+)进行了颗粒物的分级收集,对其质量粒径分布、元素分布特性以及颗粒物微观形貌进行了讨论分析.结果表明:2种煤样燃烧生成的颗粒物均呈现双模态分布,沙尔湖煤的细颗粒物产率明显高于准东煤;细模态颗粒物的主要成分是Na和Cl,准东煤与沙尔湖煤产生的PM10中的Cl占原煤中C1质量的11.8%和28.9%,Na占煤灰中Na质量的2.66%和7.53%;高含量的碱金属和Cl会促进细颗粒物生成,沙尔湖原煤中的Cl大量迁徙进入颗粒物中,对细模态颗粒的生成贡献较大.
Study on the formation characteristics of fine particulate matter under the combustion condition of high-alkali and high-chlorine coal in Xinjiang
In order to compare the particle formation characteristics of typical high-alkali and high-chlorine Xinjiang coal under combustion conditions,a three-stage high temperature drop tube furnace was used to carry out the combustion experiment of Zhundong coal(ZD)and Shaerhu coal(SEH)in air atmosphere.The characteristics of particulate matter after combustion were analyzed.Particulate matters were collected by Dekati low pressure impactor+(DLPI+)and the mass-based particle size distribution,elemental compositions and morphology were discussed.The results showed that the particulate matter produced by the combustion of the two coal samples presents a double-peaked model.The fine particle yield of SEH is significantly higher than that of ZD.The main components of sub-micron particles were Na and Cl.The Cl in PM10 accounts for 11.8%and 28.9%of the Cl content in ZD and SEH raw coal,and Na accounts for 2.66%and 7.53%of the Na content in ZD and SEH coal ash.High levels of alkali metals and Cl promoted the formation of fine particles.A large amount of Cl in SEH raw coal migrated into particles and contributed greatly to the formation of sub-micron particles.

high-chlorine coalhigh-alkali coalparticulate matteralkali metalcoal combustion

许猛、马金荣、王建江、魏博、陈丽娟、安田田

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新疆大学化工学院,新疆煤炭清洁转化与化工过程重点实验室,新疆 乌鲁木齐 830017

新疆新业能源化工有限责任公司,新疆 五家渠 831300

高氯煤 高碱煤 颗粒物 碱金属 煤燃烧

新疆维吾尔自治区煤的灰化学理论基础及应用创新团队新疆维吾尔自治区天池英才-青年博士项目

2023D1401051052300571

2024

热力发电
西安热工研究院有限公司,中国电机工程学会

热力发电

CSTPCD北大核心
影响因子:0.765
ISSN:1002-3364
年,卷(期):2024.53(1)
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