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有机固废和煤掺烧对重金属及颗粒物生成的影响研究

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有机固体废弃物(OSW)中含有多种重金属,燃烧过程会随烟气排放,造成一定的环境危害,因此对OSW和褐煤掺混燃烧过程灰分中的重金属迁移和颗粒物生成特性进行了实验研究.结果表明:燃料在燃烧过程中各种重金属的释放不单取决于燃料本身的质量浓度,而且和高温作用下的化学机制密切相关;混合燃料烟气中产生Pb、Cd、As元素的含量明显低于典型燃料和校核燃料单独燃烧时烟气中产生的重金属元素含量;而 Cu、Zn、Co、Mn在飞灰中均有较高质量分数;800、850℃下选用的4 种燃料制得的灰分的粒径分布均大致呈现单峰正态分布;当温度升高到 900℃后,除产生小粒径灰分外,还可能会产生较大粒径的灰分颗粒.
Effect of organic solid waste and coal mixed firing on the formation of heavy metals and particulate matter
Rapidly growth of organic solid waste(OSW)has caused serious social and environmental issues.Co-combustion is an economical and environmental method to treat OSW.However,there will be a variety of heavy metals discharged with flue gas during combustion as OSW contains them.Therefore,this study conducted an experiment on the migration of heavy metals and generation of micro particles during the co-combustion of OSW and lignite.The results show that,the release of heavy metals during combustion not only depends on the concentration of heavy metal the fuel contains,but also on the chemical mechanism at high temperature.The content of Pb,Cd and As in the flue gas of blending fuel is obviously lower than that of sole OSW,but Cu,Zn,Co and Mn shows opposite tendency.In addition,the particle size distribution of the four fuels all shows a normal distribution at 800℃and 850℃,but large particle size generates when the combustion temperature rises to 900℃.

organic solid wastemixing firingheavy metalash particle sizecoal

吴有兵、杨阳、梁祖雄、巩鹏、王璟、王正江、张江涛、李小军、李亚娟、伊锦昊、刘虎

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华能陇东能源有限责任公司正宁电厂,甘肃 庆阳 745306

西安西热水务环保有限公司高效灵活煤电及碳捕集利用封存全国重点实验室,陕西 西安 710054

西安交通大学能源与动力工程学院,陕西 西安 710049

有机固废 掺烧 重金属 灰分粒径

中国华能集团有限公司总部科技项目陕西省自然科学基金项目

HNKJ21-H442020JQ-063

2024

热力发电
西安热工研究院有限公司,中国电机工程学会

热力发电

CSTPCD北大核心
影响因子:0.765
ISSN:1002-3364
年,卷(期):2024.53(2)
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