热力发电2024,Vol.53Issue(4) :28-35.DOI:10.19666/j.rlfd.202310158

基于SOFC尾气供热的甲烷重整制氢反应器模拟及实验研究

Simulation and experimental study on a methane steam reforming reactor heated by SOFC exhausted gas

李晓洁 田彭杰 周剑武 夏天 张光学
热力发电2024,Vol.53Issue(4) :28-35.DOI:10.19666/j.rlfd.202310158

基于SOFC尾气供热的甲烷重整制氢反应器模拟及实验研究

Simulation and experimental study on a methane steam reforming reactor heated by SOFC exhausted gas

李晓洁 1田彭杰 1周剑武 1夏天 1张光学2
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作者信息

  • 1. 浙江浙能技术研究院有限公司浙江省太阳能利用及节能技术重点实验室,浙江 杭州 311121
  • 2. 中国计量大学能源工程研究所,浙江 杭州 310018
  • 折叠

摘要

设计了一种千瓦级新型甲烷重整制氢反应器,采用固态氧化物燃料电池尾气供热,充分利用尾气中的余热和可燃成分,构成紧凑的高效天然气发电系统.采用计算流体力学(CFD)对反应器内燃烧及重整反应进行了数值模拟,结果表明:固态氧化物燃料电池阳极和阴极尾气能够在反应器中稳定燃烧,形成1 486 ℃高温火焰,为甲烷水蒸气重整反应供热;重整管内水蒸气和甲烷体积分数沿程不断降低,由于水蒸气过量,出口处水蒸气体积分数为35%,出口氢气体积分数为45%,甲烷转化率达到90%左右;镍催化剂具有很高的导热系数,因此重整管内外温差小于15 ℃;利用实验获得了反应器内温度、甲烷体积分数及甲烷转化率等数据,对比模拟结果验证了数值模拟的准确性.

Abstract

A new kilowatt-class methane reforming hydrogen production reactor is designed,using solid oxide fuel cell exhaust gas for heat supply.The system can make full use of the waste heat and combustible components in the exhaust gas to form a compact and efficient natural gas power generation system.Computational fluid dynamics was used to numerically simulate the combustion and reforming reactions in the reactor.The results show that the solid oxide fuel cell anode and cathode exhaust gases can be stably burned in the reactor to form a high-temperature flame of 1 486 ℃ to provide heat for the methane steam reforming reaction.In the reaction tube,the concentrations of H2O and CH4 continue to decrease along the way.Due to excess water vapor,the H2O volume concentration at the outlet is 35%,the hydrogen concentration volume fraction is 45%,and the methane conversion rate reaches 90%.Nickel catalyst has a high thermal conductivity,so the temperature difference between the inside and outside of the reaction tube is less than 15 ℃.At the same time,experimental research was used to obtain data such as temperature,methane concentration and methane conversion rate in the reactor.The simulation results were compared to verify the accuracy of the numerical simulation.

关键词

SOFC尾气/甲烷重整/制氢/计算流体力学

Key words

SOFC exhausted gas/methane steam reforming/hydrogen production/CFD

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基金项目

浙江省尖兵计划项目(2023C01124)

浙能集团科技项目(ZNKJ-2022-051)

出版年

2024
热力发电
西安热工研究院有限公司,中国电机工程学会

热力发电

CSTPCD北大核心
影响因子:0.765
ISSN:1002-3364
参考文献量25
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