首页|纤维素-SiO2的制备及在净化变压器油中的应用

纤维素-SiO2的制备及在净化变压器油中的应用

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变压器绝缘油在电力设备运行过程中会逐渐劣化,导致变压器油电气性能、理化性能大幅降低.采用吸附相反应技术,将亲水SiO2纳米颗粒固载在微晶纤维素(microcrystalline cellulose,MCC)上,制备出具有高吸附性能的改性纤维素集尘体材料,联合静电吸附技术净化处理脏污变压器油.对于SiO2改性纤维素集尘体材料,通过油品净化效果测试得出,最佳的制备条件为溶胀后干燥12h,作为硅源的正硅酸乙酯(TEOS)加入量为6g;将上述条件下合成的改性纤维素集尘体材料,置于静电净油反应器内,二者协同净化脏污变压器油后,油品的主要运行指标如水分由最初的32.0 mg/L以上降至23.5 mg/L以下,且其他包括介质损耗因数、酸值和体积电阻率等关键指标也均已达到运行油的国家标准.可见,静电技术结合改性纤维素吸附材料能够有效吸附油中的杂质颗粒.
Preparation of cellulose-SiO2 and its application in purifying transformer oil
Transformer insulating oil will gradually deteriorate during the operation of power equipment,resulting in a significant reduction in the electrical,physical and chemical properties of transformer oil.In this paper,the adsorption phase reaction technology is used to solidify hydrophilic SiO2 nanoparticles on microcrystalline cellulose(MCC),to prepare modified cellulose dust collector materials with high adsorption performance,to purify and treat dirty transformer oil by combining with electrostatic adsorption technology.For the SiO2 modified cellulose dust collector material,it can be concluded through the oil purification effect test that,the best preparation condition is dissolution and drying for 12 h,and adding 6 g ethyl orthosilicate(TEOS)as a silicon source.Then,the modified cellulose dust collector material prepared above conditions is placed in the electrostatic oil purification reactor.After synergistically purified by the two methods,the transformer oil's main operational indicators such as moisture reduces from 32.0 mg/L(the initial value)to 23.5 mg/L or less,and other key indexes including medium loss factor,acid value and volume resistivity have reached the national standard of operational oil.It shows that the electrostatic technology combined with modified cellulose adsorbent material can effectively adsorb the impurity particles in the oil.

celluloseSiO2 modified celluloseelectrostatic oil purification technologytransformer oiladsorbent material

杨雪、张春波、王浩然、孙东平、祖文轩、孙墨杰

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吉林省电力科学研究院有限公司,吉林 长春 130000

东北电力大学化学工程学院,吉林 吉林 132000

纤维素 SiO2改性纤维素 静电净油技术 变压器油 吸附材料

吉林省科技发展计划吉林省电力科学研究院有限公司科技项目

20210201058GXKY-GS-22-01-06

2024

热力发电
西安热工研究院有限公司,中国电机工程学会

热力发电

CSTPCD北大核心
影响因子:0.765
ISSN:1002-3364
年,卷(期):2024.53(5)
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