热喷涂技术2024,Vol.16Issue(1) :64-70.DOI:10.3969/j.issn.1674-7127.2024.01.006

粉体制备工艺对Gd、Yb改性YSZ热障涂层性能的影响

Influence of Powder Preparation Process on Performance of Gd and Yb Modified YSZ Thermal Barrier Coatings

邹旸 梁加宽 龚文娟 韩日飞 史天杰 庞小肖 贾芳
热喷涂技术2024,Vol.16Issue(1) :64-70.DOI:10.3969/j.issn.1674-7127.2024.01.006

粉体制备工艺对Gd、Yb改性YSZ热障涂层性能的影响

Influence of Powder Preparation Process on Performance of Gd and Yb Modified YSZ Thermal Barrier Coatings

邹旸 1梁加宽 1龚文娟 1韩日飞 2史天杰 2庞小肖 2贾芳2
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作者信息

  • 1. 中国航发南方工业有限公司,湖南株洲 412002
  • 2. 矿冶科技集团有限公司,北京 100160;北矿新材科技有限公司,北京 102206
  • 折叠

摘要

随着航空航天技术的快速发展,飞行器热端部件的服役温度越来越高,YSZ热障涂层已经无法满足目前航空发动机热端部件的服役需求,稀土元素钆(Gd)与镱(Yb)对YSZ进行掺杂得到的Gd2O3-Yb2O3-Y2O3共稳定氧化锆(GYYZO)被广泛认为在超高温工况下具有广阔的应用前景.采用固相反应法与化学沉淀法分别制备了两种球形GYYZO粉末,并采用大气等离子喷涂法制备了两种GYYZO陶瓷热障涂层,研究了粉末制备工艺对粉体结构以及涂层结构与性能的影响.结果表明,在相同喷涂参数下,基于化学共沉淀合成GYYZO粉体制备涂层顶层孔隙率更高,该涂层比固相反应合成GYYZO粉体制备的涂层具有更好的抗热震性能.

Abstract

With the rapid development of aerospace technology,the operating temperature of hot-end components of aircraft is becoming increasingly higher.YSZ thermal barrier coatings can no longer meet the service requirements of current aircraft engine hot-end components.Gd2O3-Yb2O3-Y2O3 co-stabilized zirconia(GYYZO),obtained by doping YSZ with rare earth elements gadolinium(Gd)and ytterbium(Yb),is widely considered to have broad application prospects in ultra-high temperature conditions.In this research,two types of spherical GYYZO powders were synthesized using solid-state reaction and chemical precipitation methods respectively,and two variants of GYYZO ceramic thermal barrier coatings were fabricated through the atmospheric plasma spraying technique.The effects of powder preparation process on powder structure and coating structure and properties were studied.The results show that under the same plasma spraying technique,the coating prepared by chemical co-precipitate synthesis of GYYZO powder has higher top layer porosity,and the coating has better thermal shock resistance than the coating prepared by solid reaction synthesis of GYYZO powder.

关键词

热障涂层/热震/稀土改性/热喷涂/YSZ

Key words

thermal barrier coating/thermal shock/rare-earth modification/thermal spray/YSZ

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出版年

2024
热喷涂技术
北京矿冶研究总院

热喷涂技术

影响因子:0.913
ISSN:1674-7127
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