天然薄荷醇改性聚丙烯酸酯防细菌黏附剂的制备及其在棉织物中的应用
Preparation of natural menthol modified polyacrylate anti-bacte-rial adhesive agent and its application on cotton fabric
赵小敏 1王莉莉 1吴明华 1李惠军2
作者信息
- 1. 浙江理工大学生态染整技术教育部工程中心,浙江杭州 310018
- 2. 杭州华丝夏莎纺织科技有限公司,浙江杭州 311199
- 折叠
摘要
利用天然小分子薄荷醇(MT)的立体防细菌黏附功能,通过酯化反应将其接枝到丙烯酸酐(AC)上,继而聚合生成新型含MT防细菌黏附侧链的聚丙烯酸酯共聚物[P(MAC-co-AA)].采用浸轧法处理棉织物,赋予棉织物优良的防细菌黏附效果.结果表明,当MT和AC物质的量比为2∶1,反应温度为70℃,反应时间为5h时,P(MAC-co-AA)酯化率高达70.9%,对大肠杆菌和金黄色葡萄球菌的防细菌黏附效果最好.相比MT,P(MAC-co-AA)的最大分解温度由130℃提高到252℃,其热稳定性大幅提升.当P(MAC-co-AA)整理液用量为20 g/L时,P(MAC-co-AA)整理棉织物对大肠杆菌和金黄色葡萄球菌的防细菌黏附率高达99.9%.
Abstract
The natural small molecule menthol(MT)with three-dimensional anti bacterial adhesion function was grafted onto acrylic anhydride(AC)by esterification.A new type of polyacrylate copolymer[P(MAC-co-AA)]containing MT anti-bacterial adhesion side chains was synthesized.Then the cotton fabric was treated by dipping and padding meth-od,which imparted the cotton fabric with excellent anti-bacterial adhesion effect.The results showed that when the molar ratio of MT and AC was 2∶1,the reaction temperature was 70℃,and the reaction time was 5 h,the esterification rate of P(MAC-co-AA)reached up to 70.9%.It had the best anti-bacterial adhesion effect on E.coli and S.aureus.Compared with MT,the maximum decomposition temperature of P(MAC-co-AA)increased from 130℃ to 252℃,and its thermal stability was greatly improved.When the concentration of P(MAC-co-AA)solution was 20 g/L,the anti-bacterial adhesion rate of cotton fabric finished by P(MAC-co-AA)to E.coli and S.aureus arrived at 99.9%.
关键词
薄荷醇/丙烯酸酐/防细菌黏附/棉织物Key words
menthol/acrylic anhydride/anti-bacterial adhesion/cotton fabric引用本文复制引用
出版年
2024
国家科技期刊平台
NSTL
万方数据