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氢对体心立方Fe中位错与Cr析出相相互作用的影响

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作为第四代核反应堆结构材料的Fe-Cr基铁素体/马氏体钢,在服役环境中由于嬗变反应产生大量氢原子而导致过早失效。本文利用最近发展的Fe-Cr-H三元体系的角度依赖势函数,基于分子动力学研究了氢对体心立方Fe中刃位错与Cr析出相相互作用的影响。结果表明,氢原子降低了位错的临界脱钉扎应力。在较低应变率(5×107 s-1、2×107 s-1)下,氢显著降低了临界脱钉扎应力,而在较高应变率(108 s-1)下,氢引起的临界应力变化并不显著。当析出相间距较小时,氢减低临界脱钉扎应力的幅度较大,反之亦然。
Effect of hydrogen on the interaction between dislocation and Cr precipitate in BCC Fe
Fe-Cr-based ferritic/martensitic(FM)steels,used as structural materials for the fourth generation nuclear reactors,are subjected to premature failure due to the generation of large amounts of hydrogen atoms caused by transmutation reactions in the service environment.In this paper,the effect of hydrogen on the inter-action between the edge dislocations and Cr precipitates in BCC Fe was investigated based on molecular dy-namics using the recently developed angle-dependent potential(ADP)of the Fe-Cr-H ternary system.The re-sults show that hydrogen atoms reduce the critical depinning stress required for dislocation to detach from the Cr precipitate.Under lower strain rates(5×107 s-1,2×107 s-1),hydrogen reduces the critical debonding stress significantly,while under higher strain rates(108 s-1),the hydrogen-induced change of the critical stress is not significant.The smaller is the distance between precipitates,the larger is the critical depinning stress of hydrogen reduction,and vice versa.

Hydrogen embrittlementDislocation/precipitate interactionCr precipitateMolecular dynamics

何杰、赵凯、张修路

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西南科技大学核科学技术学院,绵阳 621010

江南大学机械工程学院,无锡 214122

江苏省食品先进制造装备技术重点实验室,无锡 214122

宜宾学院计算物理四川省高等学校重点实验室,宜宾 644000

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氢脆 位错/析出相相互作用 Cr析出相 分子动力学

国家自然科学基金国家自然科学基金宜宾学院计算物理四川省高等学校重点实验室开放基金江苏省自然科学基金

4157407612102145ybxyjswlzd-2020-007BK20210444

2024

四川大学学报(自然科学版)
四川大学

四川大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.358
ISSN:0490-6756
年,卷(期):2024.61(3)