西华大学学报(自然科学版)2025,Vol.44Issue(1) :1-27.DOI:10.12198/j.issn.1673-159X.5727

低铂纳米电催化材料的设计合成及其在电催化析氢中的研究进展

Design and Synthesis of Low Platinum Nanoelectrocatalytic Materials and Progress in Electrocatalytic Hydrogen Evolution

郭晓辉 姚虎
西华大学学报(自然科学版)2025,Vol.44Issue(1) :1-27.DOI:10.12198/j.issn.1673-159X.5727

低铂纳米电催化材料的设计合成及其在电催化析氢中的研究进展

Design and Synthesis of Low Platinum Nanoelectrocatalytic Materials and Progress in Electrocatalytic Hydrogen Evolution

郭晓辉 1姚虎1
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作者信息

  • 1. 西北大学化学与材料科学学院,陕西西安 710069
  • 折叠

摘要

氢气(H2)具有较高的能量密度和绿色"零"碳特性,被认为是未来最有前途的能源替代品之一.电解水制氢提供了一种绿色、可持续的制氢途径.铂(Pt)基材料被认为是析氢反应(HER)的有效电催化剂,但是有限的储量和高昂的价格使得Pt基催化剂的大规模商业化应用受到限制;因此,设计低成本和高HER性能的低Pt电催化剂受到了广泛关注.本文总结了合金策略、强金属-载体相互作用、单原子策略等具有代表性的低Pt催化剂合成策略,系统梳理了低Pt电催化剂的研究现状.文章指出新型低Pt催化剂的设计、催化剂构效关系、新型载体材料的开发以及催化剂在实际系统中的稳定性和可靠性研究是未来研究方向.

Abstract

Hydrogen(H2)is considered one of the most promising energy alternatives for the future due to its high energy density and green"zero"carbon properties.H2 production from water electrolysis of-fers a green and sustainable way to produce H2.Platinum(Pt)-based materials are considered to be effect-ive electrocatalysts for hydrogen evolution reaction(HER),but limited metal reserves and high prices have limited the large-scale commercialization of Pt-based catalysts;therefore,the design of low-Pt electrocata-lysts that achieve low cost and high HER performance has attracted much attention.This review summar-izes representative low-Pt catalyst synthesis strategies such as alloy strategy,strong metal support interac-tions,and single-atom strategy.The research status of low platinum electrocatalysts was systematically re-viewed.It is pointed out that the design of new low Pt catalysts,the structure-activity relationship of cata-lysts,the development of new carrier materials and the stability and reliability of catalysts in actual systems are the future research directions.

关键词

析氢反应/低Pt催化剂/合金/强金属-载体相互作用/单原子

Key words

HER/low Pt catalysts/alloys/strong metal-carrier interactions/single atoms

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出版年

2025
西华大学学报(自然科学版)
西华大学

西华大学学报(自然科学版)

CSTPCD
影响因子:0.412
ISSN:1673-159X
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