西华大学学报(自然科学版)2025,Vol.44Issue(1) :28-41.DOI:10.12198/j.issn.1673-159X.5726

质子交换膜水电解制氢阳极铱基催化剂的研究进展

Research Progress in Iridium-Based Anode Catalysts for PEMWE in Hydrogen Production

黄婷 陈星雨 许雪丽 黄涛 方延延 王功名
西华大学学报(自然科学版)2025,Vol.44Issue(1) :28-41.DOI:10.12198/j.issn.1673-159X.5726

质子交换膜水电解制氢阳极铱基催化剂的研究进展

Research Progress in Iridium-Based Anode Catalysts for PEMWE in Hydrogen Production

黄婷 1陈星雨 1许雪丽 1黄涛 1方延延 1王功名1
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作者信息

  • 1. 中国科学技术大学化学系,安徽 合肥 230026
  • 折叠

摘要

氢能作为一种清洁、高效、可再生的能源,在我国能源绿色低碳转型过程中具有重要的战略地位.质子交换膜水电解(PEMWE)制氢技术因其工作电流密度大、能量效率高以及动态响应快等优势,被认为是一种极具发展前景的制绿氢技术.然而,受限于该系统核心组件之一阳极铱基催化剂的资源稀缺性和高昂成本,PEMWE在产业界仍难以得到大规模应用.针对这一问题,研究者们致力于探索兼具经济性和高效的铱基催化剂,实现PEMWE大规模应用时面临的降本增效问题.本文介绍了 PEMWE制氢的基本原理、系统构成和相应功能,从金属型、氧化物型及负载型3个角度详细综述了铱基催化剂在PEMWE制氢阳极析氧反应中的应用现状,重点讨论形貌调控、结构设计和载体选择对催化性能的影响,并提出未来应致力于开发低铱载量且高活性和稳定性的催化剂.

Abstract

As a clean,efficient and renewable energy source,hydrogen energy plays vital roles in China's strategy for the green-oriented transition of energy.Meanwhile,due to the high operational current density,high superior energy efficiency and rapid dynamic response features,proton exchange membrane water electrolysis(PEMWE)technology is gaining increasing attention as a promising method for green and sustainable hydrogen production.Nevertheless,limited by the scarcity and high cost of iridium-based catalysts,which is one of the core components of PEMWE systems,the large-scale application of PEMWE in industrial production is still far from achievable.To meet challenges,great efforts have been made to de-velop more economical and efficient iridium-based catalysts,to achieve the cost reduction and efficiency improvement issues faced by large-scale application of PEMWE.This review article systematically sum-marizes the latest advancements of iridium-based anode catalysts for PEMWE.First,the fundamental prin-ciples,system configurations and their functions of PEMWE are introduced for better understanding this hydrogen production system.Then,the current application statuses of iridium-based catalysts in the anodic oxygen evolution reaction of PEMWE hydrogen production have been elaborated,including the metal-type,oxide-type and supported-type catalysts.Focus on discussing the influence of morphology control,structur-al design,and carrier selection on catalytic performance,and propose that future efforts should be dedicated to developing catalysts with low iridium loadings,high activity,and stability.

关键词

析氧反应/质子交换膜水电解/制绿氢技术/铱基催化剂/膜电极

Key words

oxygen evolution reaction/proton exchange membrane water electrolysis/green hydrogen production technology/iridium-based catalyst/membrane electrode

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出版年

2025
西华大学学报(自然科学版)
西华大学

西华大学学报(自然科学版)

CSTPCD
影响因子:0.412
ISSN:1673-159X
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