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面向副产氢的金属氢化物分离法净化氢技术的经济性分析

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在当前"双碳"目标实施的重要阶段,氢能的重要性不断提升。在当前廉价工业副产氢存量大,市场对高纯氢气需求日益增大的背景下,基于工业副产氢纯化制取高纯氢气(氢气纯度大于99。999%)总体正处于中试示范阶段,而制氢成本是其在高纯氢制取市场形成竞争力的关键。文章建立金属氢化物分离法净化氢技术的平准化氢气制取成本(LCOHP)模型,对处理量为2000 Nm3/h规模的工业副产氢纯化制氢系统进行经济性分析,并对影响LCOHP值的主要因素进行讨论,结果表明,金属氢化物纯化制氢系统LCOHP值为1。013元/标方,其中工业副产氢原料气成本占比最高(78。45%)。此外,系统氢气回收率、工业副产氢价格、储氢材料再生费用对LCOHP值影响显著。氢气回收率每上升5%,LCOHP值下降0。012~0。042元/标方,降幅1。18%~4。15%;工业副产氢价格每上升0。05元/标方,LCOHP值上升0。101元/标方,升幅9。97%;储氢材料再生费用每降低10%,LCOHP值下降0。033元/标方,降幅约为3。26%。
Economic Analysis of Hydrogen Purification Technology by Metal Hydride Separation for By-product Hydrogen
During the current important stage of implementing the"dual carbon"target,the import-ance of hydrogen energy is constantly increasing.In response to the current large stock of cheap industrial by-product hydrogen and the increasing demand for high-purity hydrogen in the market,the purification of industrial by-product hydrogen to produce high-purity(over 99.999%)hydrogen is currently in the pilot demonstration stage.The cost of hydrogen production is the key to its competitiveness in the high-purity hydrogen production market.A novel metal hydride purification hydrogen production levelized cost of hy-drogen production model(LCOHP)is established in this work,to quantitatively analyze an industrial by-product hydrogen purification hydrogen production system with a processing capacity of 2000 Nm3/h.Moreover,the main factors affecting the LCOHP value are discussed.The results show that the LCOHP of the metal hydride purification hydrogen production system is 1.013 yuan/Nm3,among them,the cost of feed gas accounts for the highest proportion(78.45%).The system hydrogen recovery rate,industrial by-product hydrogen price,and hydrogen storage material regeneration cost have a significant impact on LCOHP.For every 5%increase in hydrogen recovery rate,the LCOHP value decreases by 0.012~0.042 yuan/standard cubic meter,a decrease of 1.18%to 4.15%.For every 0.05 yuan/standard cubic meter increase in the price of industrial by-product hydrogen,the LCOHP value increases by 0.101 yuan/standard cubic meter,an in-crease of 9.97%.For every 10%reduction in the cost of hydrogen storage material regeneration,the LCOHP decreases by 0.033 yuan/standard cubic meter,a decrease of approximately 3.26%.

metal hydridepurified hydrogen productionlevelized cost of hydrogen productioneconomic analysis

吴震、肖浩哲、刘洪皓、王劭璁

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西安交通大学化学工程与技术学院,陕西西安 710049

金属氢化物 纯化制氢 平准化氢气制取成本模型 经济性分析

2025

西华大学学报(自然科学版)
西华大学

西华大学学报(自然科学版)

影响因子:0.412
ISSN:1673-159X
年,卷(期):2025.44(1)