水处理技术2025,Vol.51Issue(1) :34-39,46.DOI:10.16796/j.cnki.1000-3770.2025.01.006

硼酸盐改性凹凸棒土制备壳聚糖-羟乙基纤维素气凝胶吸附罗丹明B染料性能研究

Chitosan-Hydroxyethyl Cellulose Aerogels Prepared from Borate-Modified Attapulgite for the Adsorption of Rhodamine B Dye

欧红香 邓林蕾 孙伟凯 陈子威
水处理技术2025,Vol.51Issue(1) :34-39,46.DOI:10.16796/j.cnki.1000-3770.2025.01.006

硼酸盐改性凹凸棒土制备壳聚糖-羟乙基纤维素气凝胶吸附罗丹明B染料性能研究

Chitosan-Hydroxyethyl Cellulose Aerogels Prepared from Borate-Modified Attapulgite for the Adsorption of Rhodamine B Dye

欧红香 1邓林蕾 1孙伟凯 1陈子威1
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作者信息

  • 1. 常州大学环境与安全工程学院,江苏 常州 213164
  • 折叠

摘要

采用四硼酸钠(STB)改性ATP,引入硼酸基团提高了材料对染料的选择性,后与壳聚糖(CS)和羟乙基纤维素(HEC)交联,制备STB-ATP@CS-HEC气凝胶,用于去除罗丹明B染料(RhB).理化表征结果表明,该气凝胶具有良好的溶胀性,60 min达到溶胀平衡,溶胀率为1 172.5%.基于准二级模型、Temkin和Freundlich等温线模型,可以较好地描述气凝胶对RhB染料的吸附行为,主要是化学多分子层吸附.在303 K时,将20 mg材料投加到50 mL初始浓度为250 mg/L的RhB染料中,吸附量178.83 mg/g.材料有良好的吸附再生能力,在染料废水处理领域具有良好的应用前景.

Abstract

Sodium tetraborate was utilized for modifying the intaglio clay,introducing the boric acid group to enhance the material's selectivity towards the dye.It was then cross-linked with chitosan and hydroxyethyl cellulose to fabricate STB-ATP@CS-HEC aerogel,intended for the removal of rhodamine B dye.The physicochemical characterization results revealed favorable swelling properties of the aerogel,reaching equilibrium within 60 minutes at a swelling ratio of 1 172.5% .The adsorption behavior of the aerogel on rhodamine B dye could be accurately described using the quasi-secondary model,Temkin and Freundlich isotherm models,primarily indicating chemical monomolecular layer adsorption.When 20 mg of the 303 K material was introduced into 50 mL of RhB dye with an initial concentration of 250 mg/L,the adsorption amount reached 178.83 mg/g.The material exhibited promising adsorption regeneration capability,thus demonstrating its potential for application in dye wastewater treatment.

关键词

凹凸棒土/硼酸盐/壳聚糖/羟乙基纤维素/罗丹明B/吸附

Key words

attapulgite/borate/chitosan/hydroxyethyl cellulose/Rhodamine B/adsorption

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出版年

2025
水处理技术
杭州水处理技术研究开发中心有限公司

水处理技术

CSCD北大核心
影响因子:0.731
ISSN:1000-3770
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