首页|硼酸盐改性凹凸棒土制备壳聚糖-羟乙基纤维素气凝胶吸附罗丹明B染料性能研究

硼酸盐改性凹凸棒土制备壳聚糖-羟乙基纤维素气凝胶吸附罗丹明B染料性能研究

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采用四硼酸钠(STB)改性ATP,引入硼酸基团提高了材料对染料的选择性,后与壳聚糖(CS)和羟乙基纤维素(HEC)交联,制备STB-ATP@CS-HEC气凝胶,用于去除罗丹明B染料(RhB)。理化表征结果表明,该气凝胶具有良好的溶胀性,60 min达到溶胀平衡,溶胀率为1 172。5%。基于准二级模型、Temkin和Freundlich等温线模型,可以较好地描述气凝胶对RhB染料的吸附行为,主要是化学多分子层吸附。在303 K时,将20 mg材料投加到50 mL初始浓度为250 mg/L的RhB染料中,吸附量178。83 mg/g。材料有良好的吸附再生能力,在染料废水处理领域具有良好的应用前景。
Chitosan-Hydroxyethyl Cellulose Aerogels Prepared from Borate-Modified Attapulgite for the Adsorption of Rhodamine B Dye
Sodium tetraborate was utilized for modifying the intaglio clay,introducing the boric acid group to enhance the material's selectivity towards the dye.It was then cross-linked with chitosan and hydroxyethyl cellulose to fabricate STB-ATP@CS-HEC aerogel,intended for the removal of rhodamine B dye.The physicochemical characterization results revealed favorable swelling properties of the aerogel,reaching equilibrium within 60 minutes at a swelling ratio of 1 172.5% .The adsorption behavior of the aerogel on rhodamine B dye could be accurately described using the quasi-secondary model,Temkin and Freundlich isotherm models,primarily indicating chemical monomolecular layer adsorption.When 20 mg of the 303 K material was introduced into 50 mL of RhB dye with an initial concentration of 250 mg/L,the adsorption amount reached 178.83 mg/g.The material exhibited promising adsorption regeneration capability,thus demonstrating its potential for application in dye wastewater treatment.

attapulgiteboratechitosanhydroxyethyl celluloseRhodamine Badsorption

欧红香、邓林蕾、孙伟凯、陈子威

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常州大学环境与安全工程学院,江苏 常州 213164

凹凸棒土 硼酸盐 壳聚糖 羟乙基纤维素 罗丹明B 吸附

2025

水处理技术
杭州水处理技术研究开发中心有限公司

水处理技术

北大核心
影响因子:0.731
ISSN:1000-3770
年,卷(期):2025.51(1)