水处理技术2025,Vol.51Issue(1) :152-156.DOI:10.16796/j.cnki.1000-3770.2025.01.026

30GWh/年三元软包锂电池生产企业综合废水处理工程实例

Triple Soft Pack Lithium Battery Manufacturing Plant(Annual Output of 30GWh)Wastewater and Waste Gas Treatment Project

晋存田 刘政 王文菊 戚伟康 宋建阳
水处理技术2025,Vol.51Issue(1) :152-156.DOI:10.16796/j.cnki.1000-3770.2025.01.026

30GWh/年三元软包锂电池生产企业综合废水处理工程实例

Triple Soft Pack Lithium Battery Manufacturing Plant(Annual Output of 30GWh)Wastewater and Waste Gas Treatment Project

晋存田 1刘政 2王文菊 1戚伟康 3宋建阳4
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作者信息

  • 1. 中交公路规划设计院有限公司,北京 100088
  • 2. 北京铭泽源环境工程有限公司,北京 100101
  • 3. 北京工业大学城镇污水深度处理与资源化利用技术国家工程实验室,北京 100124
  • 4. 南阳理工学院,河南省工业微生物资源与发酵技术重点实验室,河南 南阳 473004
  • 折叠

摘要

三元软包锂电池企业产生的废水能否达标处理,关系到企业能否正常生产及可持续性发展.以江西某地实际工程为例,实际总产水300 m3/d,设计规模为370 m3/d.产生的生产废水主要包括正负极生产废水和电芯拆解废水,具有COD高,难生物降解以及含有氟化物、总镍、总锰和总钴的特点.工程运行结果表明:经过两级混凝+厌氧的工艺处理后的污水,再和厂区其他污水混合后经过接触氧化池+MBR工艺组合处理,出水水质优于≤电池工业污染物排放标准≥(GB 30484-2013)表2中废水间接排放标准.整个处理系统长期运行稳定,操作简单,两性离子纳米平板陶瓷膜MBR具有膜通量大的优点.经过核算,处理费用为5.7元/方.本案例的长期稳定达标可为同类企业的废水处理提供参考.

Abstract

The sustainability of a lithium battery manufacturing plant depends on whether the final effluent meets discharge standards.This project,located in Jiangxi Province,involved the treatment of 300 m3/d of wastewater,with a design capacity of 370 m3/d.The wastewater from the triple soft-pack lithium battery manufacturing process primarily consisted of production wastewater from positive and negative electrodes and cell disassembly.It was characterized by high COD concentrations,low biodegradability,and the presence of fluoride and heavy metals(Ni,Mn,Co).The treatment process involved two stages:initial coagulation and anaerobic treatment,followed by mixing with other wastewater streams and further treatment through contact oxidation and a membrane bioreactor(MBR).The quality of the final effluent exceeded the emission standards set by the"Pollutants Emission Standards for the Battery Industry Wastewater"(GB30484-2013)in Table 2 of the indirect emission quality standards.An innovative zwitterionic flat ceramic membrane,with higher hydrophilicity and a higher L/day per m2(LMH)and lower chemical cleaning frequency,was used in the submerged MBR system.The water treatment cost was estimated at only 5.7 Yuan/m3.

关键词

三元软包锂电池生产废水/两级混凝/浸没式MBR/两性离子平板陶瓷膜/工程分析

Key words

triple soft pack lithium battery manufacturing wastewater/two-stage coagulation/submerged mbr system/zwitterion flat ceramic membrane/instance analysis

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出版年

2025
水处理技术
杭州水处理技术研究开发中心有限公司

水处理技术

北大核心
影响因子:0.731
ISSN:1000-3770
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