首页|热处理对铸态Fe-Cr-W-B合金微观结构与力学性能的影响

热处理对铸态Fe-Cr-W-B合金微观结构与力学性能的影响

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Fe-W-B系合金具有优异的核辐射屏蔽效果,在添加一定量的Cr元素后,原本粗大的脆性硼化物组织得到了一定的细化,但其塑韧性等力学性能依然较差.为进一步改善Fe-Cr-W-B合金的微观结构和力学性能,本文引入1200 ℃保温1 h的热处理工艺,研究其对铸造Fe-Cr-W-B合金微观结构和力学性能的影响.结果表明,铸态Fe-Cr-W-B合金以α-(Fe,Cr,W)为基体,以M3B2(M=W,Cr,Fe)为硼化物析出相,硼化物在晶界处呈连续网状分布,因而合金在变形过程中易形成应力集中而产生微小裂纹以致断裂,使得Fe-Cr-W-B合金塑韧性极差.经过1200 ℃保温1 h的热处理后,Fe-Cr-W-B合金基体中的过饱和W原子扩散进入硼化物,基体的固溶强化效应减弱,硬度降低,合金强度略有下降;但硼化物体积收缩,晶界处的连续网状结构断开,硼化物弥散分布,Fe-Cr-W-B合金的塑韧性得到较大改善.
Effect of heat treatment on microstructure and mechanical properties of as-cast Fe-Cr-W-B alloy
Fe-W-B alloys have excellent nuclear radiation shielding effect,but poor mechanical properties.The Fe-Cr-W-B alloy powder produced by adding Cr element has relatively fine boride microstructure.In order to further im-prove the microstructure and mechanical properties of Fe-Cr-W-B alloy,this paper investigates the effect of heat treatment at 1200 ℃ for 1 h on the microstructure and mechanical properties of cast Fe-Cr-W-B alloy.The results show that the as-cast Fe-Cr-W-B alloy is composed of α-(Fe,Cr,W)as matrix and M3B2(M=W,Cr,Fe)as boride precipitated phase.The boride is distributed in a continuous network at the grain boundary,which causes stress con-centration in the matrix during deformation,resulting in extremely poor ductility and toughness of Fe-Cr-W-B alloy.After heat treatment at 1200 ℃ for 1h,W atoms in Fe-Cr-W-B alloy matrix enters the boride,solid solution strengthening effect is weakened,reducing the hardness and strength;the boride volume shrinks,the continuous mesh structure at the grain boundary is broken,and the ductility and toughness of Fe-Cr-W-B alloy is improved.

Fe-Cr-W-B alloyboridemechanical propertymicrostructureheat treatment

侯浪、李军、刘颖

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四川大学材料科学与工程学院,四川成都 610065

Fe-Cr-W-B合金 硼化物 力学性能 微观结构 热处理

2024

四川冶金
四川省冶金情报标准研究所

四川冶金

影响因子:0.165
ISSN:1001-5108
年,卷(期):2024.46(4)
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