首页|Tamm溶液提取-石墨炉原子吸收光谱法测定土壤中有效钼

Tamm溶液提取-石墨炉原子吸收光谱法测定土壤中有效钼

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提出了 Tamm溶液提取-石墨炉原子吸收光谱法对土壤样品中有效钼的测定方法.有效钼标准曲线的相关系数为0.9995,方法检出限为0.005 mg/kg,定量限为0.018 mg/kg;采用有证标准物质对方法适用性进行了考察,本方法测定值与认定值基本一致,且相对误差(RE)不大于4.17%,相对标准偏差(RSD)不大于7.87%,本方法检出限低、精密度和正确度较好,满足土壤样品测试工作的要求,简化了工作流程,提高了工作效率,适用于批量土壤样品中有效钼的测定.
Determination of Available Molybdenum in Soil by Tamm Solution Extraction and Graphite Furnace Atomic Absorption Spectrometry
A method for the determination of available molybdenum in soil samples by Tamm solution ex-traction and graphite furnace atomic absorption spectrometry has been presented.The correlation coeffi-cient of available molybdenum standard curve is 0.9995,the detection limit is 0.005mg/kg,and the quanti-tation limit is 0.018mg/kg.The applicability of the method has been investigated by using certified refer-ence materials.The measured value of the method is basically consistent with the certified value,the rela-tive error(RE)is less than 4.17%,and the relative standard deviation(RSD)is less than 7.87%.The de-tection limit of the method is low,the precision and accuracy are good,which will meet the requirements of soil sample testing and simplified the work flow.The work efficiency has been improved.It is suitable for the determination of available molybdenum in batch soil samples.

Available molybdenumsoilgraphite furnace atomic absorption spectrometry

辜洋建、高玉花、陈璐、张同生、宋传洪、毕建玲、王玉环

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山东省物化探勘查院,山东省地矿局中心实验室,山东省地质勘查工程技术研究中心,地下资源环境高精度探测山东省工程研究中心,山东 济南 250013

济南大学化学化工学院,山东 济南 250022

有效钼 土壤 石墨炉原子吸收光谱法

院科技攻关计划(2023)

KY202307

2024

山东国土资源
山东省地质科学实验研究院

山东国土资源

影响因子:0.385
ISSN:1672-6979
年,卷(期):2024.40(2)
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