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热重及热显微镜测定超细煤粉着火点的研究

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研究不同测定及计算方法对煤粉着火点数值的影响能够为理论研究及工业应用提供指导。文章选取了3 种具有代表性的煤——铁岭褐煤、内蒙古烟煤、河南无烟煤,经超细化粉碎得到了不同粒径的样品,分别置于空气、纯氧、二氧化碳富氧、氮气富氧等气氛中,在热显微镜下研究样品的着火点;利用热重分析仪,在空气气氛下获得了10 和 20℃/min升温速率下的热重曲线,使用切线法及固定失重率法获得了着火点数据。结果表明:氮气富氧气氛比二氧化碳富氧气氛更有利于着火,超细化对无烟煤着火改善的作用最明显;在相同升温速率下,热重切线法得到的着火点数值高于固定失重法,且明显高于热显微镜直观观测到的数值;利用热重法分析着火点发现,升温速率越大,着火点数值越高,但是着火所需时间更短。
Study on the ignition point of superfine pulverized coal by the thermogravimetry and thermal microscope
Investigating the impact of different measurements and calculation methods on the ignition point of pulverized coal is essential for guiding both theoretical researches and industrial applications.This study involved three representative types of coal—Tieling lignite,Inner Mongolia bituminous coal and Henan anthracite.The coal samples were finely pulverized to achieve varying particle sizes.These samples were then exposed to different atmospheres,including air,pure oxygen,carbon dioxide-enriched oxygen and nitrogen-enriched oxygen,and their ignition points were examined using a thermal microscope.Additionally,thermogravimetric curves were obtained at heating rates of 10 and 20℃/min using a termogravimetric analyzer.The ignition point data were derived through the tangent and Constant-DTG method.The results reveal that a nitrogen-enriched oxygen atmosphere is more favorable for ignition compared to a carbon dioxide-enriched oxygen atmosphere.Furthermore,superfine pulverization demonstrates the most significant improvement in lowering the ignition temperature for anthracite.At the same heating rate,the ignition point obtained by the thermogravimetric tangent method surpasses that obtained by the fixed weight-loss method and notably exceeds the values observed through thermal microscopy.The thermogravimetric analysis indicates that with a higher temperature rise rate,the ignition point value increases,but the required ignition time decreases.

ignition pointsuperfine pulverized coalcombustionthermogravimetrythermal microscope

马阳、闫敏

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山东建筑大学 热能工程学院,山东 济南 250101

煤粉着火点 超细煤粉 燃烧 热重 热显微镜

山东建筑大学博士科研基金项目

X21015Z

2024

山东建筑大学学报
山东建筑大学

山东建筑大学学报

影响因子:0.576
ISSN:1673-7644
年,卷(期):2024.39(1)
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