首页|离子共掺对钛酸锶光催化性能的影响

离子共掺对钛酸锶光催化性能的影响

扫码查看
钛酸锶(SrTiO3)光催化剂是一种钙钛矿型氧化物,具有氧化还原能力强和环境友好的特点,在分解水制氢、有机污染物降解等领域得到广泛应用.通过水热法制备SrTiO3 光催化剂,并采用Pr/N共掺杂优化其能带结构.分析催化剂结构、形貌、比表面积和光催化析氢速率,以评估Pr/N共掺杂对SrTiO3 性能的影响.结果显示,与未掺杂的SrTiO3 相比,Pr/N-SrTiO3 的禁带宽度Eg减小了0.3 eV;析氢速率为3.552 mmol·g-1·h-1,提高62.3倍,且具有良好的循环稳定性.共掺杂离子Pr/N的存在延长了SrTiO3 的载流子寿命,提高了载流子的分离效率.
Effect of ionic co-doping on photocatalytic performance of strontium titanate
SrTiO3 photocatalyst,as a kind of perovskite oxide,is featured by strong REDOX ability and environmental friendliness and has been widely used in the fields of hydrogen production by water decomposition and degradation of organic pollutants.The photocatalyst SrTiO3 was prepared by hydrothermal method and the band structure was optimized by Pr/N co-doping.The structure,morphology,specific surface area and photocatalytic hydrogen evolution rate of the catalyst were analyzed to evaluate the effect of Pr/N co-doping on the performance of SrTiO3.The results show that with the forbidden band width Eg decreasing by 0.3 eV and the hydrogen precipitation rate increasing by 62.3 times to 3.552 mmol·g-1·h-1,Pr/N-SrTiO3 has a better cyclic stability compared with undoped SrTiO3.The presence of co-doped ions,Pr/N,prolongs the lifetime of carriers and improves the separation efficiency of carriers in SrTiO3.

ionic co-dopingPr/N-SrTiO3SrTiO3photocatalysishydrogen production

赵凯欣、赵子豪、王龙、谈博文、田秀娟

展开 >

山东科技大学 材料科学与工程学院,山东 青岛 266590

离子共掺 Pr/N-SrTiO3 SrTiO3 光催化 制氢

山东省科技型中小企业创新能力提升工程项目

SKDZK20230113

2024

山东科技大学学报(自然科学版)
山东科技大学

山东科技大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.437
ISSN:1672-3767
年,卷(期):2024.43(4)
  • 3