首页|淮南矿区焦煤自燃指标气体及极限参数的研究

淮南矿区焦煤自燃指标气体及极限参数的研究

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为分析淮南矿区焦煤的自燃预测气体指标,探究其自燃极限参数的变化规律,选择淮南矿区五种焦煤作为实验样本,采用程序升温实验装置对煤样低温氧化过程中的气体产生量及气体比值变化趋势进行研究,分析煤自燃的极限参数.实验结果表明:在低温氧化的过程中,CO、C2H6 和C2H4 产生量均随着温度的增加而逐渐增加,并且CO产生量随温度表现出指数增加的趋势;当CO/CO2 比值大于 0.1 时,各煤样的温度均超过了约 100℃,煤自燃已经发展到了快速氧化阶段.C2H4/C2H6 比值在 100~130℃范围内为不稳定阶段,超过 130℃后开始稳定增长;煤低温氧化过程中的极限氧浓度和最小浮煤厚度均随着温度的增加表现出先增加后降低的趋势且在 50℃处达到最大值;在相同的温度条件下,极限氧浓度与煤厚度呈反比关系,最大漏风强度与煤厚度则表现出正比的关系;随着漏风强度的增加,最小浮煤厚度也呈现出逐渐增加的趋势.
Research on the Index Gas and Limit Parameters of Spontaneous Combustion of Coking Coal in Huainan Mining Area
To analyze the spontaneous combustion prediction gas index of coking coal in Huainan mining area and explore the variation law of its spontaneous combustion limit parameters,five types of coking coal in Huainan mining area are selected as experimental samples.The programmed temperature experimental device is used to study the gas production amount and gas ratio change trend during the low-temperature oxidation process of coal samples,and to analyze the limit parameters of coal spontaneous combustion.The experimental results show that during the process of low-temperature oxidation,the production amount of CO,C2H6,and C2H4 gradually increases with the increase of temperature,and the production amount of CO shows an exponential increase trend with temperature;When the CO/CO2 ratio is greater than 0.1,the temperature of each coal sample exceeds about 100℃,and coal spontaneous combustion developes into a rapid oxidation stage.The C2H4/C2H6 ratio is in an unstable stage within the temperature range of 100-130℃,and begins to steadily increase after exceeding 130℃;The ultimate oxygen concentration and minimum floating coal thickness during the low-temperature oxidation process of coal show a trend of first increasing and then decreasing with the increase of temperature,and reach their maximum value at 50℃;Under the same temperature conditions,the ultimate oxygen concentration is inversely proportional to coal thickness,while the maximum air leakage intensity is directly proportional to coal thickness;With the increase of air leakage intensity,the minimum floating coal thickness also shows a gradually increasing trend.

coking coalcoal spontaneous combustiongas indexgas ratiolimit parameter

吴晓茹

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中煤能源研究院有限责任公司,陕西 西安 710054

焦煤 煤自燃 气体指标 气体比值 极限参数

2024

山东煤炭科技
山东省煤炭学会

山东煤炭科技

影响因子:0.185
ISSN:1005-2801
年,卷(期):2024.42(9)
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