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南四湖支流东鱼河水质现状及健康风险评价

Water Quality and Environmental Health Risk Assessment of Dongyu River

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为了解南四湖集流面积最大的入湖河流——东鱼河水质及其健康风险水平,自上游至入湖口采集表层水样,测定了盐度(SAL)、溶解氧(DO)、溶解性有机碳(DOC)、N、P、Hg和As的含量,并采用美国国家环保局(US EPA)推荐的健康风险评价模型,评价了其通过饮水途径产生的健康风险.结果表明,东鱼河水体中DO、As、NH3、TP、Hg的平均含量分别为9.39、0.002 6、0.61、0.27、0.000 25 mg/L;各点位DO和As含量均达到Ⅲ类水标准,Hg、TP、NH3的超标率依次为90.9%、45.5%、18.2%,Hg的平均含量为标准值的2.5倍;各指标具有显著的沿程变化,主要表现为中下游N、P和有机污染较为严重,DOC与各形态N、P间存在显著的相关性,As分别与DOC和NO2呈显著正相关和负相关关系;东鱼河水体中致癌物As的健康风险值为0.31×10-5~5.04×10 5/a,占总健康风险值的99.95%以上,介于US EPA和部分机构推荐的最大可接受风险水平1.0×10-6~1.0×10-4/a之间.
Dongyu River is the main tributary with the largest watershed area flowing into Nansi Lake.In order to understand the water quality and health risk level of Dongyu River,surface water samples were collected from the upper river to the river outlet.Concentrations of dissolved organic carbon (DOC),nitrogen,phosphorus,mercury (Hg),arsenic (As) dissolved oxygen (DO) and salinity were analyzed.Health risk of the pollutants via drinking the water in Dongyu River was evaluated by using the models of US EPA.The results show that the average concentrations of DO,As,ammonium (NH3),total phosphorus (TP) and Hg are 9.39 mg/L,0.002 6 mg/L,0.61 mg/L,0.27 mg/L and 0.000 25 mg/L respectively.DO and As concentrations at each sampling site meet the requirements of type Ⅲ standard in the GB3838-2002 National Environmental Quality Standards for Surface Water,while Hg,TP and NH3 concentrations exceed the standard values in 90.9 %%,45.5 %,and 18.2 % of the sampling sites respectively.Moreover,the average concentration of Hg was 2.5 times of the standard value.Each parameter has a significant spatial change along the river;generally high concentrations of nitrogen,phosphorus and organic matters are found in the middle and lower reaches of Dongyu River.DOC is significantly correlated with nitrogen and phosphorus,while As is positively correlated with DOC but negatively correlated with nitrite (NO-2).The carcinogenic health risk values of As is in the range of 0.31 × 10-5-5.04 × 10-5/a,which accounts for more than 99.95% of the total health risk.The total hcalth risk of As,NH3,Hg,NO-3 is within the range of the up-limit tolerant level of 10-6-10-4/a recommended by US EPA and other organizations.

water qualityhealth risk assessmentDongyu RiverNansi Lake

张菊、鲁长娟、郭娜、董杰、殷山红、邓焕广、杨会会

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聊城大学环境与规划学院,山东聊城252000

北京航空航天大学化学与环境学院,北京100191

水质 健康风险评价 东鱼河 南四湖

国家自然科学基金山东省自然科学基金山东省自然科学基金

41401563ZR2014JL028ZR2013DL003

2017

水电能源科学
中国水力发电工程学会 华中科技大学 武汉国测三联水电设备有限公司

水电能源科学

CSTPCD北大核心
影响因子:0.525
ISSN:1000-7709
年,卷(期):2017.35(8)
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