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烷基酚聚氧乙烯醚对混凝土中钢筋氯盐耐蚀性的影响

Effect of Alkylphenol Polyoxyethylene Ether on Corrosion Resistance of Chloride Salts for Steel Bars in Concrete

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为研究不同浓度的烷基酚聚氧乙烯醚(APEO)缓蚀阻锈效果,开展钢筋电化学试验,研究不同APEO浓度对钢筋电化学行为和缓蚀效果的影响.结果表明,随着APEO浓度的增加,钢筋的电化学行为出现三阶段变化特征,即激发—抑制—再激发;当APEO浓度达30 mg/L时,腐蚀溶液中钢筋表面阻抗最大,腐蚀电流最小,电化学反应强度最弱;当APEO浓度过低时,在钢筋表面难以形成包裹完整的钝化膜;当APEO浓度过高时,作为金属络合物的APEO易与钢筋表面Fe发生络合反应,加剧钢筋腐蚀反应.因此,掺入一定浓度的APEO,可有效提高钢筋抗腐蚀性,延长钢筋混凝土结构在Cl-腐蚀环境下的服役寿命.
To study the corrosion and rust inhibition effects of alkylphenol polyoxyethylene ether(APEO)at different concentrations,electrochemical tests were conducted on steel bars to investigate the influence of different APEO concen-trations on the electrochemical behavior and corrosion inhibition effect of steel bars.The results show that with the in-crease of APEO concentration,the electrochemical behavior of steel bars exhibits a three-stage change characteristics:ex-citation,inhibition and re-excitation;When the APEO concentration reaches 30 mg/L,the surface impedance of the steel bar in the corrosion solution is the highest,the corrosion current is the lowest,and the electrochemical reaction intensity is the weakest;When the APEO concentration is too low,it is difficult to form a complete passivation film on the surface of the steel bar;When the concentration is too high,APEO,as a metal complex,is prone to complexation reaction with Fe on the surface of steel bars,exacerbating the corrosion reaction of steel bars.Therefore,adding a certain concentration of APEO can effectively improve the corrosion resistance of steel bars and prolong the service life of reinforced concrete structures in Cl-corrosive environments.

alkylphenol polyoxyethyleneCl-corrosioncorrosion inhibitionimpedance spectrumconcentration-dependent

刘伟

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中铁十九局集团第一工程有限公司,辽宁 辽阳 111000

烷基酚聚氧乙烯醚 Cl-腐蚀 阻蚀 阻抗谱 浓度依赖性

西南交通大学与中铁十九局集团第一工程有限公司合作科技项目

CR1901-NCGJGSGLSG2-03

2024

水电能源科学
中国水力发电工程学会 华中科技大学 武汉国测三联水电设备有限公司

水电能源科学

CSTPCD北大核心
影响因子:0.525
ISSN:1000-7709
年,卷(期):2024.42(10)
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