首页|碱熔-离子选择电极法测定含铁尘泥中的F含量

碱熔-离子选择电极法测定含铁尘泥中的F含量

扫码查看
含铁尘泥样品采用NaOH熔融并溶解于水中,使样品中的F有效融出.以茜素红S溶液为指示剂,用盐酸(1+1)与NaOH溶液调节溶液pH,加入柠檬酸钠缓冲溶液,调节溶液pH在5~6,用氟离子选择电极测定其电位值,计算样品中F含量.实验结果表明,按照本方法测定含铁尘泥中的F含量,测定结果的相对标准偏差(RSD,n=8)均≯3.00%;加标回收率为95%~110%.
Determination of Fluorine in Metallurgical Ferric Dust by Alkali Fusion-Ion Selective Electrode Method
Metallurgicalferricdust was fused by NaOH and dissolved in water.Fluorine in the sample was effectively melted out.The pH of the solution was adjusted by hydrochloric acid(1+1)and NaOH solution with alizarin red S solution as the indicator.Then the pH of the solution was adjusted between 5 and 6 by adding sodium citrate buffer solution.The potential value was measured with the fluoride ion selective electrode to calculate the content of fluorine in the sample.The results indicate that the relative standard deviations(RSD,n=8)of measured results were less than 3.00%and the recoveries were between 95%-110%.

ion selective electrodemetallurgicalferricdustfluorinalkali fusio

丁晓彤

展开 >

山东省冶金科学研究院有限公司,山东 济南 250102

离子选择电极 含铁尘泥 碱熔

2024

山东冶金
山东金属学会

山东冶金

影响因子:0.176
ISSN:1004-4620
年,卷(期):2024.46(6)