首页|用铁矾渣吸附去除废水中Mo(Ⅵ)试验研究

用铁矾渣吸附去除废水中Mo(Ⅵ)试验研究

扫码查看
研究了以锌浸出液沉铁后的铁矾渣为吸附材料去除废水中Mo(Ⅵ),考察了模拟废水初始pH和Mo(Ⅵ)初始质量浓度、铁矾渣用量、吸附时间对铁矾渣吸附Mo(Ⅵ)的影响,并探讨了吸附动力学.结果表明:在废水中Mo(Ⅵ)初始质量浓度40 mg/L、pH=3.0、吸附剂用量1.0 g/L、吸附时间240 min条件下,铁矾渣对Mo(Ⅵ)的吸附量可达13.21 mg/g;铁矾渣对废水中Mo(Ⅵ)的吸附过程更适合用准二级动力学模型描述,属于化学吸附;铁矾渣吸附钼过程更遵循Langmuir等温吸附模型,有较高的拟合精度,吸附过程属于单层分子吸附.该法工艺简单,成本较低,有望实现废渣高值化循环利用.
Adsorption and Removal of Mo(Ⅵ)from Wastewater by Jarosite
The removal of Mo(Ⅵ)from wastewater was studied by using jarosite after iron deposition in zinc leaching solution as adsorption material.The effects of the initial pH of simulated wastewater,the initial mass concentration of Mo(Ⅵ),the additon amount of jarosite and the adsorption time on the adsorption of Mo(Ⅵ)by jarosite were investigated,and the kinetic mechanism of the adsorption process was discussed.The results show that under the conditions of initial mass concentration of Mo(Ⅵ)of 40 mg/L,pH=3.0,additon amount of jarosite of 1.0 g/L and adsorption time of 240 min,the adsorption capacity of Mo(Ⅵ)can reach 13.21 mg/g.The adsorption process of Mo(Ⅵ)in wastewater by jarosite is more suitable to be described by quasi-second-order kinetic model,which belongs to chemical adsorption.The adsorption process of molybdenum by jarosite follows the Langmuir isothermal adsorption model and has higher fitting accuracy.The adsorption process belongs to monolayer molecular adsorption.This method has the advantages of simple process and low cost,and is expected to realize high-value recycling of waste residue.

jarositeadsorptionremovalwaste watermolybdenumdynamicsmechanism

曾军、王夏、李昕、张忠培、吴艳喆、彭慧、谢雪珍、叶有明

展开 >

广西科技师范学院食品与生化工程学院,广西 来宾 546199

广西无机材料绿色制备与应用重点试验室,广西来宾 546199

铁矾渣 吸附 去除 废水 动力学 机制

广西科技计划项目广西重点实验室运行补助项目2022年广西大学生创新创业训练计划项目

桂科AD2029713921-220-09S202211546070

2024

湿法冶金
核工业北京化工冶金研究院

湿法冶金

北大核心
影响因子:0.631
ISSN:1009-2617
年,卷(期):2024.43(1)
  • 20