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脱磷渣中有价元素在不同有机酸溶液中的浸出行为

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脱磷渣中含有大量CaO、SiO2、FeO、P2O5等有价组元,具有作为土壤改良剂和肥料的潜力.为了推动脱磷渣在农业中的应用,有必要了解其在有机酸溶液中的浸出行为.考察了pH和有机酸类型对脱磷渣中各有价元素浸出率的影响规律.结果表明:脱磷渣中的主要矿物相为富铁相(RO相)、CaFeSiO4基体相和C2S-C3P固溶体;渣中Ca、Si元素主要分布在含磷固溶体和基体相中,P元素富集在C2S-C3P相中,Fe元素主要分布在RO相中;pH降低可明显促进脱磷渣溶解,大部分脱磷渣能在枸橼酸溶液中溶解;在pH=5时,Ca、Si、Mg元素浸出率约为90%,P浸出率达68.84%,实现了有价元素的浸出.
Dissolution Behavior of Valuable Elements from Dephosphorization Slag in Different Kinds of Organic Acids
Dephosphorization slag contains a large amount of valuable components such as CaO,SiO2,FeO,P2O5,etc.,and has the potential to be used as soil amendment and fertilizer.To promote utilization of dephosphorization slag in agriculture,it is necessary to understand its dissolution behavior in the organic acid solution.The influence of pH and organic acid type on the dissolution ratios of various valuable elements from dephosphorization slag was investigated.The results show that the main mineral phases in the dephosphorization slag are RO phase,CaFeSiO4 matrix phase,and C2S-C3P solid solution.Ca and Si elements in the slag are mainly distributed in the C2 S-C3 P solid solution and CaFeSiO4 matrix phase,while the P element is enriched in the C2S-C3P solid solution.Fe element is mainly distributed in the RO phase.As the pH value decreased,the dissolution of slag is significantly promoted,and most of the dephosphorization slag can be dissolved in the citric acid solution.At pH=5,the dissolution ratios of Ca,Si,Mg elements are about 90%,and the P dissolution ratio is 68.84%,achieving the dissolution of valuable elements.

dephosphorization slagsoil amendmentvaluable elementsleachingorganic acid

蒋佳霖、李尚兵、王鑫、杜传明

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东北大学冶金学院,辽宁沈阳 110819

江苏永钢集团有限公司,江苏 张家港 215600

脱磷渣 土壤改良剂 有价元素 浸出 有机酸

国家自然科学基金中国博士后科学基金

521043262022M721415

2024

湿法冶金
核工业北京化工冶金研究院

湿法冶金

北大核心
影响因子:0.631
ISSN:1009-2617
年,卷(期):2024.43(2)
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