首页|钼的靶向吸附材料合成及其性能研究

钼的靶向吸附材料合成及其性能研究

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研究了采用真空灌注法将α-安息香肟(α-BO)固载在多孔甲基丙烯酸酯聚合物载体(PMMA-DVB)中制备钼的靶向吸附材料(α-BO/PMMA),通过红外光谱、元素分析、热重分析及光学显微镜等手段对其进行结构表征,并考察了酸种类、H+浓度、接触时间及吸附平衡时溶液中MoO22+浓度对α-BO/PMMA吸附性能的影响.结果表明:α-BO/PMMA对钼的吸附受酸度影响较大,在0.1 mol/L的盐酸介质中吸附量最高,最大吸附量为29.8 mg/g,该材料可有效分离提取钼.
Synthesis and Properties of Molybdenum Targeted Adsorption Materials
Molybdenum targeted-adsorption material(α-BO/PMMA)was prepared by vacuum infusion of α-benzoxime(α-BO)in porous poly-methacrylate carrier(PMMA-DVB),and its structure was characterized by infrared spectroscopy,elemental analysis,thermogravimetric analysis and optical microscopy.The effects of acid type,H+concentration,contact time and MoO22+ concentration on the adsorption properties of α-BO/PMMA were investigated.The results show that the adsorption capacity ofα-BO/PMMA on molybdenum is greatly affected by acidity,and the adsorption capacity is the highest in 0.1 mol/L hydrochloric acid medium,and the maximum adsorption capacity is 29.8 mg/g.The material can effectively separate and extract molybdenum.

molybdenumadsorption materialalpha-benzoximeporous carrierseparationextractioncoppertungsten

常华、宿延涛、勾阳飞、王海珍、李默、杨吴馨晨

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核工业北京化工冶金研究院,北京 101149

吸附材料 α-安息香肟 多孔载体 分离 提取

2024

湿法冶金
核工业北京化工冶金研究院

湿法冶金

北大核心
影响因子:0.631
ISSN:1009-2617
年,卷(期):2024.43(2)
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